Synthesis, structure, and catalytic activity of palladium(II) complexes of new CNC pincer-type N-heterocyclic carbene ligands

被引：87
|
作者：
Wei, Wei [1 ]
Qin, Yuancheng [1 ]
Luo, Meiming [1 ]
Xia, Pingfang [2 ]
Wong, Man Shing [2 ]
机构：
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
[2] Hong Kong Baptist Univ, Dept Chem, Kowloon Tong, Hong Kong, Peoples R China
来源：
ORGANOMETALLICS | 2008年 / 27卷 / 10期
关键词：
D O I：
10.1021/om800007s
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New CNC pincer-type N-heterocyclic carbene ligands with a central diarylamido moiety are presented. Palladium(II) pincer complexes of type [Pd(L)Cl] (L = bis[2-(3-alkylimidazolin-2-yliden-1-yl)-4-methylphenyl]amido) 5a-c (5a, alkyl = benzyl; 5b, alkyl = n-butyl; 5c, alkyl = 2,4,6-trimethylbenzyl) were obtained from the corresponding silver carbene complexes and [PdCl2(MeCN)(2)] without addition of external bases. The palladium pincer complex 5a was characterized by X-ray diffraction. The molecular structure of 5a shows a distorted square-planar coordination geometry for the palladium atom. Pincer complexes 5a-c have been shown to be active catalysts for the Suzuki-Miyaura reactions.
引用
收藏
页码：2268 / 2272
页数：5
相关论文
共 50 条
  • [31] Synthesis, structural characterization and catalytic activity of two N-heterocyclic carbene-phosphine palladium(II) complexes
    Xu, Chen
    Hao, Xin-Qi
    Li, Zhen
    Dong, Xin-Ming
    Duan, Lu-Meng
    Wang, Zhi-Qiang
    Ji, Bao-Ming
    Song, Mao-Ping
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 17 : 34 - 37
  • [32] Water-Induced Changes of Photoluminescence of a Pincer-Type N-Heterocyclic Carbene Platinum(II) Complex
    Lee, Chen-Shiang
    Sabiah, Shahulhameed
    Wang, Ju-Chun
    Hwang, Wen-Shu
    Lin, Ivan J. B.
    ORGANOMETALLICS, 2010, 29 (02) : 286 - 289
  • [33] Bidentate Chelating N-Heterocyclic Carbene Complexes of Palladium: Synthesis and Structure
    Nan, Guangming
    Qin, Yuancheng
    Wei, Zhijun
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2012, 42 (02) : 285 - 290
  • [34] Synthesis and structure of N-heterocyclic carbene complexes of germanium(II)
    Rupar, Paul A.
    Jennings, Michael C.
    Baines, Kim M.
    ORGANOMETALLICS, 2008, 27 (19) : 5043 - 5051
  • [35] Butylene linked palladium N-heterocyclic carbene complexes: Synthesis and catalytic properties
    Demir, Serpil
    Ozdemir, Ismail
    Arslan, Hakan
    VanDerveer, Don
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2011, 696 (13) : 2589 - 2593
  • [36] INOR 774-Palladium(II) difluoride complexes with chelating N-heterocyclic carbene ligands: Synthesis, structure and reactivity
    Yandulov, Dmitry V.
    Kintz, Samuel S.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232
  • [37] N-heterocyclic benzhydrylamines as new N,N-bidentate ligands in palladium complexes:: Synthesis, characterization and catalytic activity
    Terrasson, Vincent
    Prim, Damien
    Marrot, Jerome
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (17) : 2739 - 2745
  • [38] Synthesis, structure and reactivity of palladium(II) complexes of chiral N-heterocyclic carbene-imine and -amine hybrid ligands
    Bonnet, LG
    Douthwaite, RE
    Hodgson, R
    Houghton, J
    Kariuki, BM
    Simonovic, S
    DALTON TRANSACTIONS, 2004, (21) : 3528 - 3535
  • [39] Potentially Hemilabile N-Heterocyclic Carbene Palladium Complexes: Synthesis and Catalytic Applications
    Gu, Shaojin
    Chen, Chao
    Qiu, Huayu
    Chen, Wanzhi
    CURRENT ORGANIC CHEMISTRY, 2011, 15 (18) : 3291 - 3308
  • [40] Synthesis, characterization and antimicrobial activity of new silver complexes with N-heterocyclic carbene ligands
    Ozdemir, Ilknur
    Demir, Serpil
    Gunal, Selami
    Ozdemir, Ismail
    Arici, Cengiz
    Ulku, Dincer
    INORGANICA CHIMICA ACTA, 2010, 363 (14) : 3803 - 3808
12345