Electrocatalytic reduction of diethyl oximinomalonate at a Ti/nanoporous TiO2 electrode

被引：26

作者：

Chu, Daobao ^{[1
,2
]}

Xu, Mai ^{[1
]}

Lu, Jia ^{[1
]}

Zheng, Peng ^{[1
]}

Qin, Guoxu ^{[3
]}

Yuan, Ximei ^{[4
]}

机构：

[1] Anhui Normal Univ, Coll Chem & Mat Sci, Anhua 241000, Peoples R China

[2] Anhui Key Lab Funct Mol Solids, Anhua 241000, Peoples R China

[3] Coll Chaohu, Dept Chem & Mat Sci, Chaohu 238000, Peoples R China

[4] Anhui Horae New Technol Dev Co Ltd, Anhui 230088, Peoples R China

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2008年 / 10卷 / 02期

基金：

中国国家自然科学基金;

关键词：

nanoporous TiO2 electrode; diethyl acetamidomalonate; diethyl oximinomalonate; electrocatalytic reduction; buffer solution;

D O I：

10.1016/j.elecom.2007.12.022

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

A "green" method for production of diethyl aminomalonate was presented by electrocatalytic reduction of diethyl oximinomalonate (DEOM) to diethyl aminomalonate in the acetic acid and sodium acetate medium at the surface of Ti/nanoporous TiO2 electrode. The heterogeneous catalytic redox behaviour of a nanoporous TiO2 film electrode surface was investigated by cyclic voltammetry (CV). A comparison of the CV recorded in the absence and in the presence of DEOM confirmed the catalytic reduction of DEOM by Ti(IV)/Ti(III) redox system on the nanoporous TiO2 film surface. (c) 2007 Elsevier B.V. All rights reserved.

引用

页码：350 / 353

页数：4

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