Reactions of (difluoroamino)trinitromethane with nucleophilic reagents

被引：1

作者：

Khisamutdinov, GK

Shevelev, SA

机构：

[1] State Res Inst Kristall, Dzerzhinsk, Novgorod Region, Russia

[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119992, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 04期

关键词：

(difluoroamino)trinitromethane; (difluoroamino)fluorodinitromethane; bromonitro(N-fluoroimino) methane; substitution reaction;

D O I：

10.1023/A:1011345819626

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of F2NC(NO2)(3) with metal fluorides (KF and CsF) in DMF yield a substitution product of the fluorine atom for one nitro group, F2NC(NO2)(2)F. The reaction of F2NC(NO2)(3) with LiBr in ethanol or DMF affords Br(NO2)C=NF rather than the expected bromo derivative F2NC(NO2)(2)Br.

引用

页码：736 / 737

页数：2

共 10 条

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