High-temperature crystal chemistry of georgbokiite

被引：0

作者：

Krivovichev, SV ^{[1
]}

Semenova, TF ^{[1
]}

Filatov, SK ^{[1
]}

机构：

[1] St Petersburg State Univ, St Petersburg 199164, Russia

来源：

CRYSTALLOGRAPHY REPORTS | 1998年 / 43卷 / 06期

关键词：

D O I：

暂无

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Phase transformations and thermal deformations in a new mineral georgbokiite, Cu5O2(SeO3)(2)Cl-2, were studied by the X-ray diffraction method. It is shown that anisotropy of thermal expansion of georgbokiite crystals is explained most satisfactorily by the presence of oxocentered [O2Cu5] chains parallel to the c-axis of the structure. These chains consist of [OCu4]-tetrahedra sharing alternatively either their vertices or edges.

引用

页码：1003 / 1006

页数：4

共 7 条

[1] Filatov S.K., 1990, High Temperature Crystal Chemistry
[2] FILATOV SK, 1992, DOKL AKAD NAUK SSSR+, V322, P536
[3] FILATOV SK, 1994, PROGRAMMA U ROSSII G, P16
[4] CRYSTAL-STRUCTURE OF A NEW OXIDE CHLORIDE OF COPPER(II) AND SELENIUM(IV) - CU5SE2O8CL2
GALY, J
BONNET, JJ
ANDERSSON, S
[J]. ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1979, 33 (05): : 383 - 389
[5] KRIVOVICHEV SV, IN PRESS Z KRISTALLO
[6] PUSHCHAROVSKII DY, 1982, STRUKTURA SVOISTVA K
[7] VERGASOVA LP, IN PRESS DOKL AKAD N

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