Silica supported amorphous molybdenum catalysts prepared via sol-gel method and its catalytic activity

被引：43

作者：

Adam, Farook ^{[1
]}

Iqbal, Anwar ^{[1
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Sci, George Town 11800, Malaysia

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2011年 / 141卷 / 1-3期

关键词：

Amorphous molybdenum-silica catalyst; Oxidation of styrene; Sol-gel technique; Heterogeneous catalyst; Benzaldehyde; STYRENE OXIDATION; MOLECULAR-SIEVES; MCM-41; CYCLOHEXANE; EPOXIDATION; COMPLEXES; H2O2; FE;

D O I：

10.1016/j.micromeso.2010.10.037

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Silica supported amorphous molybdenum catalysts had been synthesized in alkali, neutral and acidic medium via sal-gel technique. The catalysts were found to be amorphous and free from bulk MoO3. UV-Vis diffuse reflectance analysis and XPS analysis indicated the co-existence of Mo5+ and Mo6+ species when the incorporation was done in acidic medium. The catalytic activity was tested in the liquid phase oxidation of styrene by using hydrogen peroxide as oxidant. The catalyst prepared in acidic medium showed better catalytic activity compared to the catalysts prepared in alkali and neutral medium. The co-existence of Mo5+ and Mo6+ species is believed to enhance the catalytic activity. Benzaldehyde was the major product detected. The structure of the catalyst was proposed based on the results obtained from XPS, Si-29 MAS NMR, UV-Vis diffuse reflectance and FT-IR spectroscopy. (C) 2010 Elsevier Inc. All rights reserved.

引用

页码：119 / 127

页数：9

共 50 条

[21] Gold, palladium and gold-palladium supported on silica catalysts prepared by sol-gel method: synthesis, characterization and catalytic behavior in the ethanol steam reforming
da Silva, Anderson G. M.
Robles-Dutenhefner, Patricia A.
Dias, Anderson
Fajardo, Humberto V.
Lovon, Adriana S. P.
Lovon-Quintana, Juan J.
Valenca, Gustavo P.
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2013, 67 (02) : 273 - 281
[22] Preparation of Amorphous Silica-Alumina Using the Sol-Gel Method and its Reactivity for a Matrix in Catalytic Cracking
Ishihara, Atsushi
CATALYSIS SURVEYS FROM ASIA, 2012, 16 (01) : 36 - 47
[23] Sol-gel synthesis, characterization and catalytic activity of Pd supported on silica and siloxane-modified silica
Mahmoud, SS
Arafa, IM
Sheikha, OI
ASIAN JOURNAL OF CHEMISTRY, 2000, 12 (04) : 1047 - 1056
[24] Selective cleavage of ethers using silica-alumina gel catalysts prepared by the sol-gel method
Tetrahedron, 28 (9387):
[25] Selective cleavage of ethers using silica-alumina gel catalysts prepared by the sol-gel method
Matsumoto, Y
Mita, K
Hashimoto, K
Iio, H
Tokoroyama, T
TETRAHEDRON, 1996, 52 (28) : 9387 - 9398
[26] Catalytic properties of ultrafine molybdenum-cerium oxide particles prepared by the sol-gel method
Kuang, WX
Fan, YN
Chen, Y
CATALYSIS LETTERS, 1998, 50 (1-2) : 31 - 35
[27] Catalytic properties of ultrafine molybdenum-cerium oxide particles prepared by the sol-gel method
W. Kuang
Y. Fan
Y. Chen
Catalysis Letters, 1998, 50 : 31 - 35
[28] SOL-GEL PREPARED VANADIUM SUPPORTED ON ALUMINA, SILICA, TITANIA AND MAGNESIA
LOPEZ, T
BOSCH, P
TZOMPANTZI, F
SANCHEZ, E
RAZO, L
MATERIALS LETTERS, 1995, 22 (5-6) : 259 - 263
[29] Mesoporous silica supported sulfated zirconia prepared by a sol-gel process
Akkari, R
Ghorbel, A
Essayem, N
Figueras, F
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2005, 33 (01) : 121 - 125
[30] Rietveld refinement of amorphous SiO2 prepared via sol-gel method
Martinez, J. R.
Palomares-Sanchez, S.
Ortega-Zarzosa, G.
Ruiz, Facundo
Chumakov, Yurii
MATERIALS LETTERS, 2006, 60 (29-30) : 3526 - 3529

← 1 2 3 4 5 →