A triclinic polymorph of bis(μ2-ethanethiolato)-1:2κ2S:S;3:4κ2 S:S-(μ4-disulfido-1:2:3:4κ4S:S:S′:S′)tetrakis[tricarbonyliron(II)](2 Fe-Fe)

被引：1
|
作者：
Si, Youtao [1 ]
Chen, Hui [2 ]
Chen, Chang Neng [2 ]
机构：
[1] Fujian Normal Univ, Minist Educ, Key Lab Humid Subtrop Ecogeog Proc, Fuzhou 350007, Peoples R China
[2] Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
基金：
中国国家自然科学基金;
关键词：
ACTIVE-SITE; IRON; HYDROGENASES;
D O I：
10.1107/S1600536811017405
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Next to the monoclinic polymorph [Cheng et al. (2005). Acta Cryst. E61, m892-m894], the triclinic title compound, [Fe-4(C2H5S)(2)(S-2)(CO)(12)], is the second known form of this composition. The structure is composed of an [Fe-2(C2H5S)(S)(CO)(6)] subcluster, which is linked to its counterpart by an inversion centre located at the mid-point of the central disulfide bond. The Fe2S2 core of each subcluster exhibits a butterfly-like shape, with two S atoms bridging two Fe atoms. In the subcluster, each Fe atom is coordinated in a distorted octahedral coordination by three terminal carbonyl C atoms, two S atoms and one Fe atom. The crystal packing is accomplished through van der Waals interactions.
引用
收藏
页码：M752 / U1049
页数：10
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