A triclinic polymorph of bis(μ2-ethanethiolato)-1:2κ2S:S;3:4κ2 S:S-(μ4-disulfido-1:2:3:4κ4S:S:S′:S′)tetrakis[tricarbonyliron(II)](2 Fe-Fe)

被引：1

作者：

Si, Youtao ^{[1
]}

Chen, Hui ^{[2
]}

Chen, Chang Neng ^{[2
]}

机构：

[1] Fujian Normal Univ, Minist Educ, Key Lab Humid Subtrop Ecogeog Proc, Fuzhou 350007, Peoples R China

[2] Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

中国国家自然科学基金;

关键词：

ACTIVE-SITE; IRON; HYDROGENASES;

D O I：

10.1107/S1600536811017405

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Next to the monoclinic polymorph [Cheng et al. (2005). Acta Cryst. E61, m892-m894], the triclinic title compound, [Fe-4(C2H5S)(2)(S-2)(CO)(12)], is the second known form of this composition. The structure is composed of an [Fe-2(C2H5S)(S)(CO)(6)] subcluster, which is linked to its counterpart by an inversion centre located at the mid-point of the central disulfide bond. The Fe2S2 core of each subcluster exhibits a butterfly-like shape, with two S atoms bridging two Fe atoms. In the subcluster, each Fe atom is coordinated in a distorted octahedral coordination by three terminal carbonyl C atoms, two S atoms and one Fe atom. The crystal packing is accomplished through van der Waals interactions.

引用

页码：M752 / U1049

页数：10

共 50 条

[1] (μ4-disulfido-1:2κ2S,S;3:4κ2S′,S′)bis(μ2-ethylthiolato-κ2S:S)tetrakis[tricarbonyl-iron(II)(Fe-Fe)]
Cheng, LX
Ma, CB
Hu, MQ
Chen, CN
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M892 - M894
[2] Tetrakis(μ-triisopropylsilanethiolato)-1:2κ4S:S;2:3κ4S:S-bis(triisopropylsilanethiolato)-1κS,3κS-trizinc(II)
Medina-Ramirez, Iliana E.
Fink, Mark J.
Donahue, James P.
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2009, 65 : M475 - M477
[3] Tetrakis[2-(dimethylaminomethyl)phenyl]1κC,2κC,3κC,4κC-hexa-μ-sulfido-1:2κ4S:S;1,4κ2S:S;2:3κ2S:S;3:4κ4S:S-tetratin(IV) chloroform solvate
Varga, Richard A.
Silvestru, Cristian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2789 - U1483
[4] Chromopolarizabilities of bottomonia from the Υ(2S, 3S, 4S) → Υ(1S, 2S)ππ transitions
Chen, Yun-Hua
Guo, Feng-Kun
PHYSICAL REVIEW D, 2019, 100 (05)
[5] (2S,4S)-2-[(S,E)-2-Bromo-1-nitromethyl-3-phenylallyl]-4-methylcyclohexanone
Zhao, Long
Wu, Chao
Weng, Wen-Zeng
Yan, Chu-Xia
Xia, Ai-Bao
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1253 - +
[6] Observation of Υ(4S) decays to π+π-Υ(1S) and π+π-Υ(2S)
Aubert, B
Barate, R
Bona, M
Boutigny, D
Couderc, F
Karyotakis, Y
Lees, JP
Poireau, V
Tisserand, V
Zghiche, A
Grauges, E
Palano, A
Chen, JC
Qi, ND
Rong, G
Wang, P
Zhu, YS
Eigen, G
Ofte, I
Stugu, B
Abrams, GS
Battaglia, M
Brown, DN
Button-Shafer, J
Cahn, RN
Charles, E
Gill, MS
Groysman, Y
Jacobsen, RG
Kadyk, JA
Kerth, LT
Kolomensky, YG
Kukartsev, G
Lynch, G
Mir, LM
Oddone, PJ
Orimoto, TJ
Pripstein, M
Roe, NA
Ronan, MT
Wenzel, WA
Barrett, M
Ford, KE
Harrison, TJ
Hart, AJ
Hawkes, CM
Morgan, SE
Watson, AT
Goetzen, K
Held, T
PHYSICAL REVIEW LETTERS, 2006, 96 (23)
[7] Synthesis of (2S,3R,4S),(2S,3S,4R)-epoxyprolines and aminohydroxyprolines
Robinson, JK
Lee, V
Claridge, TDW
Baldwin, JE
Schofield, CJ
TETRAHEDRON, 1998, 54 (5-6) : 981 - 996
[8] WHAT COMES IN 2S, 3S, AND 4S - AKER,S
GALDA, L
READING TEACHER, 1991, 45 (02): : 151 - 151
[9] Synthesis of (2S,4S)- and (2S,4R)-5-fluoroleucine and (2S,4S)-[5,5-2H2]-5-fluoroleucine
Charrier, JD
Hadfield, DS
Hitchcock, PB
Young, DW
ORGANIC & BIOMOLECULAR CHEMISTRY, 2004, 2 (04) : 474 - 482
[10] Simple Diastereoselective Synthesis of (2S*,2′R*,3′R*,4S*)-2,3′-Diphenylspiro[chroman-3,2′-oxiran]-4-ols and (2S*,2′S*,3′S*,4S*)-2,3′-Diphenylspiro[chroman-3,2′-oxiran]-4-ols
Mandal, Tapas K.
Chattopadhyay, Falguni
Guha, Chayan
Sepay, Nayim
Mallik, Haimanti
Mallik, Asok K.
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2018, 50 (01) : 100 - 107

← 1 2 3 4 5 →