Bis(η5-cyclopentadienyl)[μ-(4b,5,5a-η3:9b,10,10a-η3)-2,3,7,8-tetrakis(trimethylsilyl)benzo[3,4]cyclobuta[1,2-b]biphenylene]-syn-dicobalt (Co-Co), a Dinuclear π-Complex of the Linear[3]Phenylene Framework

被引：0

作者：

Padilla, Robin ^{[1
]}

Vollhardt, K. Peter C. ^{[1
]}

Houk, Kendall N. ^{[2
]}

Wong, Jonathan J. ^{[2
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

SYNLETT | 2022年 / 33卷 / 01期

基金：

美国国家科学基金会;

关键词：

aromaticity; cobalt; complexation; dinuclear complexes; phenylenes; COBALT-CATALYZED COCYCLIZATION; TRIPLE-DECKER; INTERCYCLOBUTADIENE HAPTOTROPISM; CRYSTAL-STRUCTURE; BRIDGING LIGANDS; ARENE; PHENYLENES; REACTIVITY; BENZENE;

D O I：

10.1055/a-1659-7656

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound was made by the reaction of the CpCo-complex of 2,3,7,8-tetrakis(trimethylsilyl) linear [3]phenylene, in which the metal coordinates one of the cyclobutadiene rings, with CpCo(C2H4)(2). Because of its relative stability, a syn-dicobalt-bound configuration is indicated rather than its anti alternative.

引用

页码：34 / 37

页数：4

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