Towards hydroperoxovanadium complexes:: the X-ray crystal structure of a peroxovanadium(v) complex containing a V(O2)(RCO2H)(H2O)2 cluster with hydrogen bond inter-linkages

被引：39
|
作者：
Casny, M [1 ]
Rehder, D [1 ]
机构：
[1] Univ Hamburg, Dept Chem, D-20416 Hamburg, Germany
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 10期
关键词：
D O I：
10.1039/b101010g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The molecular structure of the oxo-peroxovanadium complex [VO(O-2)(bpaH)]ClO4. 2H(2)O, containing the new ligand N,N-bis(2-pyridylmethyl)-beta -alanine (bpaH) reveals tight binding of the carboxylic acid function to the vanadium centre through its doubly bonded oxygen; the carboxylic acid proton mediates hydrogen bonding interactions comprising the peroxo group and the two waters of crystallisation, thus providing the basis for the potential formation of a hydroperoxo species.
引用
收藏
页码：921 / 922
页数：2
相关论文
共 50 条
  • [41] Hydrothermal synthesis and crystal structure of Ni(phen)(H2O)(V2O6)
    Zhou, B
    Shi, FN
    Wang, JM
    Chen, MQ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (02) : 217 - 220
  • [42] Addition of H2O and O2 to Acetone and Dimethylsulfoxide Ligated Uranyl(V) Dioxocations
    Leavitt, Christopher M.
    Bryantsev, Vyacheslav S.
    de Jong, Wibe A.
    Diallo, Mamadou S.
    Goddard, William A., III
    Groenewold, Gary S.
    Van Stipdonk, Michael J.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 113 (11): : 2350 - 2358
  • [43] Synthesis and Crystal Structure of the Mixed Metal Coordination Framework [Co2(H2O)2(pyrazine)V4O12](H2O)2
    Rachel C. Severance
    Eric S. Rountree
    Mark D. Smith
    Hans-Conrad zur Loye
    Journal of Chemical Crystallography, 2012, 42 : 997 - 1000
  • [44] Synthesis and Crystal Structure of the Mixed Metal Coordination Framework [Co2(H2O)2(pyrazine)V4O12](H2O)2
    Severance, Rachel C.
    Rountree, Eric S.
    Smith, Mark D.
    zur Loye, Hans-Conrad
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2012, 42 (10) : 997 - 1000
  • [45] Synthesis　and　Crystal　Structure　of　a　Heteronuclear　Complex［MnSc(DTPA)(H2O)2］·2H2O
    张毅
    李标国
    高松
    金天柱
    徐光宪
    JournalofRareEarths, 1995, (01) : 1 - 4
  • [46] Crystal structure of ammonium (picolinamide)oxodiperoxovanadate(V) monohydrate, NH4[VO(O2)2(C6H6N2O)] • H2O
    Pan, Yanglin
    Yu, Xianyong
    Wei, Zhanbing
    Cai, Shuhui
    Chen, Zhong
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2008, 223 (04): : 449 - 450
  • [47] Synthesis and crystal structure of the complex [Mn(phendione)(PDC)(H2O)2]•2H2O
    Ge Hong-Guang
    Sun Wu-Juan
    Guo Xiao-Hua
    Zhao Cai-Bin
    Xu Qiong
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (12) : 2111 - 2114
  • [48] Schiff base complexes of vanadium(III, IV, V) as catalysts for the electroreduction of O2 to H2O in acetonitrile
    Liu, ZH
    Anson, FC
    INORGANIC CHEMISTRY, 2001, 40 (06) : 1329 - 1333
  • [49] Synthesis and characterization of vanadium(V) complexes with α-hydroxyhippuric acid.: The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-α-hhip)(S-α-hhip)]•5H2O, [α-hhip = α-hydroxyhippurato(2-)]
    Ahmed, M
    Schwendt, P
    Sivák, M
    Marek, J
    TRANSITION METAL CHEMISTRY, 2004, 29 (06) : 675 - 680
  • [50] Synthesis and characterization of vanadium(V) complexes with α-hydroxyhippuric acid. The X-ray crystal structure of (NBu4)2[V2O2(O2)2(R-α-hhip) (S-α-hhip)]·5H2O,[α-hhip = α-hydroxyhippurato(2-)]
    Mohamed Ahmed
    Peter Schwendt
    Michal Sivá
    Jaromín Marek
    Transition Metal Chemistry, 2004, 29 : 675 - 680
12345