Towards hydroperoxovanadium complexes:: the X-ray crystal structure of a peroxovanadium(v) complex containing a V(O2)(RCO2H)(H2O)2 cluster with hydrogen bond inter-linkages

被引：39

作者：

Casny, M ^{[1
]}

Rehder, D ^{[1
]}

机构：

[1] Univ Hamburg, Dept Chem, D-20416 Hamburg, Germany

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 10期

关键词：

D O I：

10.1039/b101010g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The molecular structure of the oxo-peroxovanadium complex [VO(O-2)(bpaH)]ClO4. 2H(2)O, containing the new ligand N,N-bis(2-pyridylmethyl)-beta -alanine (bpaH) reveals tight binding of the carboxylic acid function to the vanadium centre through its doubly bonded oxygen; the carboxylic acid proton mediates hydrogen bonding interactions comprising the peroxo group and the two waters of crystallisation, thus providing the basis for the potential formation of a hydroperoxo species.

引用

页码：921 / 922

页数：2

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