Reactions of Pd(PPh3)4 with 3′,5′-di-O-acetylthymidine:: Oxidative addition of Pd(PPh3)4 on thymidine N3 and C4 atoms

被引：12

作者：

Romanelli, A

Iacovino, R

Piccialli, G

Ruffo, F

De Napoli, L

Pedone, C

Di Blasio, B

Messere, A

机构：

[1] Univ Naples 2, Dipartimento Sci Ambientali, I-81100 Caserta, Italy

[2] Univ Naples Federico II, Dipartimento Sci Biol, I-80134 Naples, Italy

[3] Univ Naples Federico II, Dipartimento Chim Sostanze Nat, I-80131 Naples, Italy

[4] Complesso Univ Monte S Angelo, Dipartimento Chim, I-80126 Naples, Italy

[5] Complesso Univ Monte S Angelo, Dipartimento Chim Organ & Biochim, I-80126 Naples, Italy

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 14期

关键词：

D O I：

10.1021/om050058s

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidative addition reactions of Pd(PPh3)(4) on the pyrimidine nucleosides 3',5'-di-O-acetylthymidine and 3',5'-di-O-acetyl-4-chlorothymidine and on the nucleobase 1-methylthymine have been investigated. N3 and C4 metal coordinated complexes 3 and 7 wend isolated and characterized by spectroscopic techniques. Moreover, the crystal structur, of the trans[PdCl(l-methyl thymine)(PPh3)(2)]center dot H2O (4) is reported.

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页码：3401 / 3406

页数：6

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