Functionalization of carbon nanotubes via Cu(I)-catalyzed Huisgen [3+2] cycloaddition "click chemistry"

被引:47
作者
Rana, Sravendra [1 ]
Cho, Jae Whan [1 ]
机构
[1] Konkuk Univ, Dept Text Engn, Seoul 143701, South Korea
关键词
NONCOVALENT FUNCTIONALIZATION; GOLD NANOPARTICLES; POLYMER; BIODEGRADATION; ARCHITECTURES; NANOCRYSTALS; POLYSTYRENE; DECORATION; SCAFFOLD; AZIDES;
D O I
10.1039/c0nr00200c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Functionalization of carbon nanotubes is essential for achieving their mechanical, electrical, and biological functions and enhancing their dispersion in a polymer matrix. Cycloaddition reactions can play a significant role as an emerging route in this direction. This minireview focuses on covalent functionalization of carbon nanotubes using a facile approach via a Cu(I)-catalyzed Huisgen [3 + 2] cycloaddition reaction. Through this reaction, an enormous variety of molecules can be coupled onto carbon nanotubes in a very controlled manner, and may be utilized for many potential applications from nanoelectronics to bio-applications.
引用
收藏
页码:2550 / 2556
页数:7
相关论文
共 66 条
[31]   Construction of linear polymers, dendrimers, networks, and other polymeric architectures by copper-catalyzed azide-alkyne cycloaddition "Click" chemistry [J].
Johnson, Jeremiah A. ;
Finn, M. G. ;
Koberstein, Jeffrey T. ;
Turro, Nicholas J. .
MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (12-13) :1052-1072
[32]   Carbon nanotubes as intracellular protein transporters: Generality and biological functionality [J].
Kam, NWS ;
Dai, HJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :6021-6026
[33]   The application of "click chemistry" for the decoration of 2(1H)-pyrazinone scaffold:: Generation of templates [J].
Kaval, N ;
Ermolat'ev, D ;
Appukkuttan, P ;
Dehaen, W ;
Kappe, CO ;
Van der Eycken, E .
JOURNAL OF COMBINATORIAL CHEMISTRY, 2005, 7 (03) :490-502
[34]  
Kolb HC, 2001, ANGEW CHEM INT EDIT, V40, P2004, DOI 10.1002/1521-3773(20010601)40:11<2004::AID-ANIE2004>3.3.CO
[35]  
2-X
[36]   Functionalization of Single-Walled Carbon Nanotubes with Azides Derived from Amino Acids Using Click Chemistry [J].
Kumar, Indresh ;
Rana, Sravendra ;
Rode, Chandrashakher V. ;
Cho, Jae Whan .
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2008, 8 (07) :3351-3356
[37]   Bandgap modulation of carbon nanotubes by encapsulated metallofullerenes [J].
Lee, J ;
Kim, H ;
Kahng, SJ ;
Kim, G ;
Son, YW ;
Ihm, J ;
Kato, H ;
Wang, ZW ;
Okazaki, T ;
Shinohara, H ;
Kuk, Y .
NATURE, 2002, 415 (6875) :1005-1008
[38]   Functionalization of single-walled carbon nanotubes with well-defined polystyrene by "click" coupling [J].
Li, HM ;
Cheng, FO ;
Duft, AM ;
Adronov, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (41) :14518-14524
[39]   Water-soluble SWCNTs from sulfonation of nanotube-bound polystyrene [J].
Li, Huaming ;
Adronov, Alex .
CARBON, 2007, 45 (05) :984-990
[40]   Bond-curvature effect of sidewall [2+1] cycloadditions of single-walled carbon nanotubes: A new criterion to the adduct structures [J].
Li, Junqian ;
Jia, Guixiao ;
Zhang, Yongfan ;
Chen, Yong .
CHEMISTRY OF MATERIALS, 2006, 18 (15) :3579-3584