Functionalization of carbon nanotubes via Cu(I)-catalyzed Huisgen [3+2] cycloaddition "click chemistry"

被引:47
作者
Rana, Sravendra [1 ]
Cho, Jae Whan [1 ]
机构
[1] Konkuk Univ, Dept Text Engn, Seoul 143701, South Korea
关键词
NONCOVALENT FUNCTIONALIZATION; GOLD NANOPARTICLES; POLYMER; BIODEGRADATION; ARCHITECTURES; NANOCRYSTALS; POLYSTYRENE; DECORATION; SCAFFOLD; AZIDES;
D O I
10.1039/c0nr00200c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Functionalization of carbon nanotubes is essential for achieving their mechanical, electrical, and biological functions and enhancing their dispersion in a polymer matrix. Cycloaddition reactions can play a significant role as an emerging route in this direction. This minireview focuses on covalent functionalization of carbon nanotubes using a facile approach via a Cu(I)-catalyzed Huisgen [3 + 2] cycloaddition reaction. Through this reaction, an enormous variety of molecules can be coupled onto carbon nanotubes in a very controlled manner, and may be utilized for many potential applications from nanoelectronics to bio-applications.
引用
收藏
页码:2550 / 2556
页数:7
相关论文
共 66 条
[1]  
[Anonymous], 2004, Carbon Nanotubes: Basic Concepts and Physical Properties
[2]  
Antoni P, 2007, CHEM COMMUN, P2249, DOI 10.1039/b703547k
[3]   Carbon-based electronics [J].
Avouris, Phaedon ;
Chen, Zhihong ;
Perebeinos, Vasili .
NATURE NANOTECHNOLOGY, 2007, 2 (10) :605-615
[4]   Covalent chemistry of single-wall carbon nanotubes [J].
Bahr, JL ;
Tour, JM .
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (07) :1952-1958
[5]   Synthesis, characterization and photophysical properties of a SWNT-phthalocyanine hybrid [J].
Ballesteros, Beatriz ;
Campidelli, Stephane ;
de la Torre, Gema ;
Ehli, Christian ;
Guldi, Dirk M. ;
Prato, Maurizio ;
Torres, Tomas .
CHEMICAL COMMUNICATIONS, 2007, (28) :2950-2952
[6]   Covalent surface chemistry of single-walled carbon nanotubes [J].
Banerjee, S ;
Hemraj-Benny, T ;
Wong, SS .
ADVANCED MATERIALS, 2005, 17 (01) :17-29
[7]   Carbon nanotubes with covalently linked porphyrin antennae: Photoinduced electron transfer [J].
Baskaran, D ;
Mays, JW ;
Zhang, XP ;
Bratcher, MS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (19) :6916-6917
[8]   Applications of carbon nanotubes in drug delivery [J].
Bianco, A ;
Kostarelos, K ;
Prato, M .
CURRENT OPINION IN CHEMICAL BIOLOGY, 2005, 9 (06) :674-679
[9]   SYNTHESIS OF THIOL-DERIVATIZED GOLD NANOPARTICLES IN A 2-PHASE LIQUID-LIQUID SYSTEM [J].
BRUST, M ;
WALKER, M ;
BETHELL, D ;
SCHIFFRIN, DJ ;
WHYMAN, R .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (07) :801-802
[10]   Probing the reversibility of sidewall functionalization using carbon nanotube transistors [J].
Cabana, Janie ;
Martel, Richard .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (08) :2244-+