A practical and highly efficient transfer hydrogenation of aryl azides using a [Ru(p-cymene)Cl2]2 catalyst and sodium borohydride

被引：6
|
作者：
Kilbas, Benan [1 ,2 ]
Yilmaz, Yunus Emre [1 ]
Ergen, Sinem [1 ]
机构：
[1] Duzce Univ, Fac Sci, Dept Chem, TR-81620 Duzce, Turkey
[2] Moltek AS Gebze Organize Sanayi, TR-41400 Gebze, Kocaeli, Turkey
来源：
COMPTES RENDUS CHIMIE | 2018年 / 21卷 / 09期
关键词：
Ru(p-cymene)Cl-2](2 ); Homogeneous catalyst; Transfer hydrogenation; Aryl azide; SUPPORTED PLATINUM; METAL-CATALYSTS; REDUCTION; COMPLEXES; PHASE; NITRO; NABH4; NANOPARTICLES; WATER; FUNCTIONALITIES;
D O I：
10.1016/j.crci.2018.07.004
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Various aniline derivatives were synthesized by selective reduction of aryl azides in the presence of a dichloro(p-cymene)ruthenium(II) dimer ([Ru(p-cymene)Cl-2](2)) via hydrolysis of sodium borohydride. The hydrogenation reactions were carried out in aqueous media at room temperature. Most of the reactions were completed within 10 min with quantitative yields. (C) 2018 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：880 / 883
页数：4
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