A practical and highly efficient transfer hydrogenation of aryl azides using a [Ru(p-cymene)Cl2]2 catalyst and sodium borohydride

被引：6

作者：

Kilbas, Benan ^{[1
,2
]}

Yilmaz, Yunus Emre ^{[1
]}

Ergen, Sinem ^{[1
]}

机构：

[1] Duzce Univ, Fac Sci, Dept Chem, TR-81620 Duzce, Turkey

[2] Moltek AS Gebze Organize Sanayi, TR-41400 Gebze, Kocaeli, Turkey

来源：

COMPTES RENDUS CHIMIE | 2018年 / 21卷 / 09期

关键词：

Ru(p-cymene)Cl-2](2 ); Homogeneous catalyst; Transfer hydrogenation; Aryl azide; SUPPORTED PLATINUM; METAL-CATALYSTS; REDUCTION; COMPLEXES; PHASE; NITRO; NABH4; NANOPARTICLES; WATER; FUNCTIONALITIES;

D O I：

10.1016/j.crci.2018.07.004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Various aniline derivatives were synthesized by selective reduction of aryl azides in the presence of a dichloro(p-cymene)ruthenium(II) dimer ([Ru(p-cymene)Cl-2](2)) via hydrolysis of sodium borohydride. The hydrogenation reactions were carried out in aqueous media at room temperature. Most of the reactions were completed within 10 min with quantitative yields. (C) 2018 Academie des sciences. Published by Elsevier Masson SAS. All rights reserved.

引用

页码：880 / 883

页数：4

共 28 条

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Deshpande, Sudhindra H.
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CATALYSIS LETTERS, 2010, 138 (3-4) : 231 - 238
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[3] Chemoselective transfer hydrogenation of nitroarenes, ketones and aldehydes using acylthiourea based Ru(II)(p-cymene) complexes as precatalysts
Sathishkumar, Pushpanathan N.
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JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 876 : 57 - 65
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Zhu, Lihua
Zheng, Jinbao
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INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (30) : 13360 - 13367
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Kara, Belguzar Yasemin
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TETRAHEDRON, 2016, 72 (39) : 5898 - 5902
[7] In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions
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Mercan, Deniz
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DALTON TRANSACTIONS, 2013, 42 (18) : 6513 - 6522
[9] Highly Efficient Chemoselective Synthesis of 2-Aryl-1-arylmethyl-1H-Benzimidazoles by Using TiCp2Cl2 Catalyst
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ORIENTAL JOURNAL OF CHEMISTRY, 2020, 36 (06) : 1173 - 1178
[10] From precursor to catalyst: the involvement of [Ru(η5-Cp*)Cl2]2 in highly branch selective allylic etherification of cinnamyl chlorides
Siddappa, Ravi Kumara Guralamatta
Chang, Chih-Wei
Chein, Rong-Jie
TETRAHEDRON LETTERS, 2014, 55 (05) : 1031 - 1035

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