Wacker oxidation of alkenes using a fluorous biphasic system. A mild preparation of polyfunctional ketones

被引：61

作者：

Betzemeier, B ^{[1
]}

Lhermitte, F ^{[1
]}

Knochel, P ^{[1
]}

机构：

[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(98)01355-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various alkenes are oxidized to the corresponding ketones using t-BuOOH in the presence of a palladium(II) catalyst bearing perfluorinated ligands using a biphasic solvent system of benzene and bromoperfluorooctane. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：6667 / 6670

页数：4

共 12 条

[1]

BACH T, 1995, LIEBIGS ANN, P855

[2] Palladium-catalyzed cross-coupling of organozinc bromides with aryl iodides in perfluorinated solvents [J].

Betzemeier, B ;

Knochel, P .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) :2623-2624

[3] Fluorous biphase systems - The new phase-separation and immobilization technique [J].

Cornils, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2057-2059

[4]

CURRAN DP, 1996, CHEMTRACTS ORG CHEM, V9, P75

[5] FACILE CATALYST SEPARATION WITHOUT WATER - FLUOROUS BIPHASE HYDROFORMYLATION OF OLEFINS [J].

HORVATH, IT ;

RABAI, J .

SCIENCE, 1994, 266 (5182) :72-75

[6]

KLEMENT I, 1997, ANGEW CHEM INT EDIT, V36, P1496

[7] Towards epoxidation catalysts for fluorous biphase systems: Synthesis and properties of two Mn(III)-tetraarylporphyrins bearing perfluoroalkylamido tails. [J].

Pozzi, G ;

Banfi, S ;

Manfredi, A ;

Montanari, F ;

Quici, S .

TETRAHEDRON, 1996, 52 (36) :11879-11888

[8] PALLADIUM-CATALYZED OXIDATION OF TERMINAL OLEFINS TO METHYL KETONES BY HYDROGEN-PEROXIDE [J].

ROUSSEL, M ;

MIMOUN, H .

JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (26) :5387-5390

[9] BRANCHED LONG-CHAIN ALKYL METHYL ETHERS - A NEW CLASS OF LIPIDS FROM SPIDER SILK [J].

SCHULZ, S ;

TOFT, S .

TETRAHEDRON, 1993, 49 (31) :6805-6820

[10] A NEW PREPARATIVE METHOD FOR 1,3-DICARBONYL COMPOUNDS BY THE REGIOSELECTIVE OXIDATION OF ALPHA,BETA-UNSATURATED CARBONYL-COMPOUNDS, CATALYZED BY PDCL2 USING HYDROPEROXIDES AS THE REOXIDANT OF PD0 [J].

TSUJI, J ;

NAGASHIMA, H ;

HORI, K .

CHEMISTRY LETTERS, 1980, (03) :257-260

← 1 2 →