Paired electrolysis for simultaneous generation of synthetic fuels and chemicals

被引:53
|
作者
Martinez, Natalia P. [1 ]
Isaacs, Mauricio [1 ,2 ,3 ]
Nanda, Kamala Kanta [1 ]
机构
[1] Pontificia Univ Catolica Chile, Fac Quim, Vicuna Mackenna 4860, Santiago 7820436, Chile
[2] Pontificia Univ Catolica Chile, Ctr Invest Nanotecnol & Mat Avanzados CIEN UC, Santiago, Chile
[3] Pontificia Univ Catolica Chile, UC Energy Res Ctr, Santiago, Chile
关键词
CARBON-DIOXIDE; HYDROGEN-PRODUCTION; H-2; EVOLUTION; ELECTROCHEMICAL CARBOXYLATION; WATER; OXIDATION; CONVERSION; REDUCTION; CO2; ELECTRODES;
D O I
10.1039/c9nj06133a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Centralized production of fuels and platform chemicals from non-fossil fuel resources using renewable energy is indispensable to curb the ever increasing global warming. To realise this vision, a distributed model based on small scale reactors needs to be constructed. In this context, electrolysers performing water splitting and carbon dioxide reduction to produce sustainable fuels carry paramount industrial importance. All these electrolysers use water oxidation as anodic half-reaction which produces oxygen having a low economic value and a higher overpotential requirement. This increases the input voltage of electrolysers. The product value and energy efficiency of these electrolysers can be further enhanced if the electrochemical hydrogen evolution and carbon dioxide reduction can be paired with alternative oxidation reactions such as biomass oxidation, electro-organic synthesis, etc., which are thermodynamically more favorable than water oxidation. This review summarizes the importance of these paired electrolysis processes for simultaneous production of fuels and value-added platform chemicals from hybrid electrolysers along with a discussion of optimization of process parameters for paired electrolysis.
引用
收藏
页码:5617 / 5637
页数:21
相关论文
共 50 条
  • [1] Recent advances in paired electrolysis of biomass- derived compounds toward cogeneration of value-added chemicals and fuels
    Liu, Hengzhou
    Li, Wenzhen
    CURRENT OPINION IN ELECTROCHEMISTRY, 2021, 30
  • [2] Seawater electrolysis for fuels and chemicals production: fundamentals, achievements, and perspectives
    Chen, Lin
    Yu, Chang
    Dong, Junting
    Han, Yingnan
    Huang, Hongling
    Li, Wenbin
    Zhang, Yafang
    Tan, Xinyi
    Qiu, Jieshan
    CHEMICAL SOCIETY REVIEWS, 2024, 53 (14) : 7455 - 7488
  • [3] Paired Electrolysis in the Simultaneous Production of Synthetic Intermediates and Substrates
    Llorente, Mark J.
    Nguyen, Bichlien H.
    Kubiak, Clifford P.
    Moeller, Kevin D.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (46) : 15110 - 15113
  • [4] Recent Advances on Electrolysis for Simultaneous Generation of Valuable Chemicals at both Anode and Cathode
    Li, Rui
    Xiang, Kun
    Peng, Zhikun
    Zou, Yuqin
    Wang, Shuangyin
    ADVANCED ENERGY MATERIALS, 2021, 11 (46)
  • [5] PRODUCTION OF SYNTHETIC FUELS BY CO-ELECTROLYSIS OF STEAM AND CARBON DIOXIDE
    Ebbesen, Sune Dalgaard
    Graves, Christopher
    Mogensen, Mogens
    INTERNATIONAL JOURNAL OF GREEN ENERGY, 2009, 6 (06) : 646 - 660
  • [6] Paired Electrolysis of Acrylonitrile and 5-Hydroxymethylfurfural for Simultaneous Generation of Adiponitrile and 2,5-Furandicarboxylic Acid
    Qi, Ji
    An, Ziying
    Chen, Xiao
    Li, Chuang
    Du, Yan
    Zhang, Xiuhong
    Liang, Changhai
    CATALYSTS, 2022, 12 (07)
  • [7] Paired electrolysis of 5-(hydroxymethyl)furfural in flow cells with a high-performance oxide-derived silver cathode
    Liu, Hengzhou
    Lee, Ting-Han
    Chen, Yifu
    Cochran, Eric W.
    Li, Wenzhen
    GREEN CHEMISTRY, 2021, 23 (14) : 5056 - 5063
  • [8] Photocatalytic Cracking of non-Biodegradable Plastics to Chemicals and Fuels
    Su, Kaiyi
    Gao, Tengshijie
    Tung, Chen-Ho
    Wu, Li-Zhu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2024, 63 (35)
  • [9] Solar Fuels and Solar Chemicals Industry
    Nocera, Daniel G.
    ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (03) : 616 - 619
  • [10] Clean hydrogen generation and storage strategies via CO2 utilization into chemicals and fuels: A review
    Bahari, Nurazni Amat
    Isahak, Wan Nor Roslam Wan
    Masdar, Mohd Shahbudin
    Yaakob, Zahira
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2019, 43 (10) : 5128 - 5150