Electrochemical synthesis and surface characterization of poly(3,4-ethylenedioxythiophene) films grown in an ionic liquid

被引：106

作者：

Ahmad, Shahzada ^{[1
]}

Deepa, M. ^{[1
]}

Singh, S. ^{[1
]}

机构：

[1] Natl Phys Lab, Elect Mat Div, New Delhi 110012, India

来源：

LANGMUIR | 2007年 / 23卷 / 23期

关键词：

D O I：

10.1021/la702442c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a facile method to synthesize poly (3,4-ethylenedioxythiophene) (PEDOT) films at room temperature in a waterproof ionic liquid, 1-ethyl-3-methylimidazolium bis(perfluoroethylsulfonyl)imide (EMIPFSI), by-electropolymerization. The ionic liquid leads to the formation of randomly oriented nanofibers and particles confined to submicrometer-sized domains in the film microstructure. X-ray photoelectron spectroscopy (XPS) and energy-dispersive X-ray (EDX) studies provide information about the intercalation of the cation apart from the reported anion in the polymer film, and on how the imidazolium ion controls the growth of PEDOT nanostructures.

引用

页码：11430 / 11433

页数：4

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