Supramolecular Isomerism in Honeycomb Metal-Organic Frameworks Driven by CH•••π Interactions: Homochiral Crystallization from an Achiral Ligand through Chiral Inducement

被引：88
|
作者：
Zhao, Xiaoliang [1 ]
He, Haiyan [1 ]
Dai, Fangna [1 ]
Sun, Daofeng [1 ]
Ke, Yanxiong [2 ]
机构：
[1] Shandong Univ, Key Lab Colloid & Interface Chem, Minist Educ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[2] E China Univ Sci & Technol, Engn Res Ctr Pharmaceut Proc Chem, Minist Educ, Sch Pharm, Shanghai 200237, Peoples R China
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 19期
关键词：
COORDINATION POLYMERS; MICROPOROUS FRAMEWORK; CRYSTAL-STRUCTURE; POROUS PROPERTY; HYDROGEN UPTAKE; NETWORK SOLIDS; HELICAL CHAINS; BUILDING-BLOCK; INCLUSION; TRANSFORMATION;
D O I：
10.1021/ic100603g
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solvothermal reaction of Zn(NO(3))(2)center dot 6H(2)O and 4,4',4 ''-(2,4,6-trimethylbenzene-1,3,5-triyl)tribenzoic acid (H(3)TMTA) in N,N'-diethylformamide or N,N-dimethylacetamide gave rise to two layered honeycomb frameworks. The different stacking arrangements of the 2D layers generate achiral (alpha-1) and chiral (beta-1) architectures, which are supramolecular isomers. The homochiral crystallization of beta-1 can be achieved through chiral inducement, which is confirmed by circular dichroism spectra.
引用
收藏
页码：8650 / 8652
页数：3
相关论文
共 41 条
  • [41] From zero to two dimensions: supramolecular nanostructures formed from perylene-3,4,9,10-tetracarboxylic diimide (PTCDI) and Ni on the Au(111) surface through the interplay between hydrogen-bonding and electrostatic metal-organic interactions
    Miao Yu
    Wei Xu
    Nataliya Kalashnyk
    Youness Benjalal
    Samuthira Nagarajan
    Federico Masini
    Erik Lægsgaard
    Mohamed Hliwa
    Xavier Bouju
    André Gourdon
    Christian Joachim
    Flemming Besenbacher
    Trolle R. Linderoth
    Nano Research, 2012, 5 : 903 - 916
12345