Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]:: A novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions

被引：31

作者：

Luo, Geng-Geng ^{[1
]}

Lin, Li-Rong

Huang, Rong-Bin

Zheng, Lan-Sun

机构：

[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China

[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

DALTON TRANSACTIONS | 2007年 / 35期

关键词：

D O I：

10.1039/b708799c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Ag(UO2)(3) (OAc)(9)][Zn(H2O)(4)(CH3CH2OH)(2)] (1, OAc = CH3-COO-) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, H-1 NMR, C-13 NMR and X-ray crystallography; it is composed of [Zn(H2O)(4)(CH3CH2OH)(2)](2+) cations and [Ag(UO2)(3-)(OAc)(9)](2-) anions in which triuranyl [(UO2)(OAc)(3)](3) clusters are linked by the Ag ion.

引用

页码：3868 / 3870

页数：3

共 30 条

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