Soret coefficients in some water-methanol, water-ethanol, and water-isopropanol systems

被引：19
作者：
Platten, J. K. [1 ]
Bou-Ali, M. M.
Blanco, P.
Madariaga, J. A.
Santamaria, C.
机构：
[1] Univ Mons, B-7000 Mons, Belgium
[2] Mondragon Univberstsitatea, Arrasate Mondragon 20500, Spain
[3] Univ Basque Country, Dept Fis Aplicada 2, E-48080 Bilbao, Spain
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2007年 / 111卷 / 39期
关键词：
D O I：
10.1021/jp074206z
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this article, we re-examine the published experimental values of the Soret coefficients of a few water-alcohol systems at a mean temperature of 37.5 degrees C, because we feel that these published values (including microgravity values) are doubtful. The main technique applied is the use of thermogravitational columns to determine the thermodiffusion coefficient. The obtained values did not agree with the published values; worse, sometimes the sign was different.
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页码：11524 / 11530
页数：7
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