Preparation of poly(styrene-block-butyl acrylate) block copolymer-silicate nanocomposites

被引:80
作者
Zhao, HY
Shipp, DA [1 ]
机构
[1] Clarkson Univ, Dept Chem, Potsdam, NY 13699 USA
[2] Clarkson Univ, Ctr Adv Mat Proc, Potsdam, NY 13699 USA
关键词
D O I
10.1021/cm034013y
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An initiator was intercalated into the interlayer spacings of montmorillonite clay, from which poly(styrene-block-butyl acrylate) silicate nanocomposites were prepared using atom transfer radical polymerization. A mixture of exfoliated structure and intercalated structure was produced in the nanocomposite. The poly(butyl acrylate) chains form microdomains with an average size of 2-5 nm.
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页码:2693 / 2695
页数:3
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