Aerobic Oxidation of Alcohols and the Synthesis of Benzoxazoles Catalyzed by a Cuprocupric Coordination Polymer (Cu+ -CP) Assisted by TEMPO

被引：102

作者：

Feng, Xun ^{[1
]}

Xu, Chen ^{[1
]}

Wang, Zhi-Qiang ^{[1
]}

Tang, Si-Fu ^{[2
]}

Fu, Wei-Jun ^{[1
]}

Ji, Bao-Ming ^{[1
]}

Wang, Li-Ya ^{[1
,3
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471022, Peoples R China

[2] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China

[3] Nanyang Normal Univ, Coll Chem & Pharm Engn, Nanyang 473601, Peoples R China

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 05期

基金：

中国国家自然科学基金;

关键词：

BENZYLIC ALCOHOLS; COMPLEXES; OXIDASE; SYSTEM;

D O I：

10.1021/ic502884z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Cu+-CP based on the tetranuclear unit {[(HSQPA)(2)Cu-4(bipy)4(]).2H(2)O}n.2nH(2)O has been constructed through Cu2+ salt, 2-(sulfonylquinlium-8-yloxy)phthalic acid (H3(S)QPA), and 4,4'-bipyridine (bipy). This Cu+-CP combined with 2,2,6,6-tetramethylpiperidine-1-oxyl as the cocatalyst is an effective catalyst for aerobic oxidation of alcohols and the synthesis of benzoxazoles and can be recycled at least four times without losing its catalytic activity.

引用

页码：2088 / 2090

页数：3

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