Visible-light-promoted C-N and C-S bonds formation: A catalyst and solvent-free photochemical approach for the synthesis of 1,3-thiazolidin-4-ones

被引:16
|
作者
Nazeef, Mohd [1 ]
Shivhare, Km Neha [1 ]
Ali, Shabir [2 ]
Ansari, Khursheed [1 ]
Ansari, Mohd Danish [1 ]
Tiwari, Saurabh K. [1 ]
Yadav, Vikas [1 ]
Siddiqui, I. R. [1 ]
机构
[1] Univ Allahabad, Dept Chem, Lab Green Synth, Allahabad 211002, Uttar Pradesh, India
[2] Aligarh Muslim Univ, Dept Chem, Aligarh 202002, Uttar Pradesh, India
关键词
Green synthesis; Mild reaction conditions; Catalyst and solvent-free protocol; Visible-light-induced multicomponent reaction; 1,3-thiazolidin-4-ones; ONE-POT SYNTHESIS; MULTICOMPONENT REACTIONS; PHOTOREDOX CATALYSIS; MEDIATED SYNTHESIS; DERIVATIVES; PHOTOCATALYSIS; INFLAMMATION; EFFICIENT; METAL; THIAZOLIDIN-4-ONES;
D O I
10.1016/j.jphotochem.2019.112347
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A visible-light-induced, one-pot mild and efficient, multicomponent-tandem synthesis of diversified 1,3-thiazolidin-4-ones under catalyst and solvent-free conditions is reported. Here, visible-light, an ideal source of energy, has been used as photochemical activator to generate C-N and C-S bonds under radical mechanistic pathway from aromatic amines, aldehydes and thioglycolic acid. The reported methodology can be extensively utilized to explore 1,3-thiazolidin-4-one derivatives with high selectivity, short reaction time, tolerance of functional groups, cost effectiveness and excellent yields.
引用
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页数:7
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