Colorimetric and ratiometric fluorescent chemodosimeter for selective sensing of fluoride and cyanide ions: tuning selectivity in proton transfer and C-Si bond cleavage

被引：36
|
作者：
Mahapatra, Ajit Kumar [1 ]
Manna, Saikat Kumar [1 ]
Pramanik, Bhaskar [2 ]
Maiti, Kalipada [1 ]
Mondal, Sanchita [1 ]
Ali, Syed Samim [1 ]
Mandal, Debasish [3 ]
机构：
[1] Indian Inst Engn Sci & Technol, Dept Chem, Howrah 711103, W Bengal, India
[2] Indian Inst Sci Educ & Res, Dept Chem Sci, Kolkata, India
[3] Hebrew Univ Jerusalem, Inst Chem, IL-91905 Jerusalem, Israel
来源：
RSC ADVANCES | 2015年 / 5卷 / 14期
关键词：
RECENT PROGRESS; CHEMOSENSORS; COMPLEXATION; RECOGNITION; THIOUREA; ANIONS; SENSOR; PROBE;
D O I：
10.1039/c4ra12910e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A simple innovative anthraimidazolyldione (LHSi) based colorimetric and ratiometric fluorescent chemodosimeter was designed and synthesized for fluoride and cyanide ion sensing. Upon reaction with the F- and CN- anions in THF solution, probe LHSi shows dramatic color changes from light yellow to red and remarkable ratiometric fluorescence enhancement signals. These properties are mechanistically ascribed to a fluoride/cyanide-triggered deprotonation and C-Si bond cleavage that resulted in a green to red fluorescence.
引用
收藏
页码：10716 / 10722
页数：7
相关论文
共 9 条
  • [1] Colorimetric and ratiometric fluorescence sensing of fluoride: Tuning selectivity in proton transfer
    Peng, XJ
    Wu, YK
    Fan, JL
    Tian, MZ
    Han, KL
    JOURNAL OF ORGANIC CHEMISTRY, 2005, 70 (25): : 10524 - 10531
  • [2] A highly selective colorimetric and ratiometric fluorescent chemodosimeter for imaging fluoride ions in living cells
    Zhu, Baocun
    Yuan, Fang
    Li, Rongxia
    Li, Yamin
    Wei, Qin
    Ma, Zhenmin
    Du, Bin
    Zhang, Xiaoling
    CHEMICAL COMMUNICATIONS, 2011, 47 (25) : 7098 - 7100
  • [3] A colorimetric and ratiometric NIR fluorescent turn-on fluoride chemodosimeter based on BODIPY derivatives: high selectivity via specific Si-O cleavage
    Cao, Jian
    Zhao, Chunchang
    Feng, Peng
    Zhang, Yulin
    Zhu, Weihong
    RSC ADVANCES, 2012, 2 (02): : 418 - 420
  • [4] Ratiometric sensing of fluoride anion through selective cleavage of Si-O bond
    Dhanunjayarao, Kunchala
    Mukundam, Vanga
    Venkatasubbaiah, Krishnan
    SENSORS AND ACTUATORS B-CHEMICAL, 2016, 232 : 175 - 180
  • [5] A highly selective colorimetric and ratiometric fluorescent chemodosimeter for detection of fluoride ions based on 1,8-naphthalimide derivatives
    Kai, Yumei
    Hu, Yonghong
    Wang, Kai
    Zhi, Wenbiao
    Liang, Mengmeng
    Yang, Wenge
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 118 : 239 - 243
  • [6] Colorimetric and ratiometric fluorescence sensing of fluoride ions based on competitive intra- and intermolecular proton transfer
    Luxami, Vijay
    Kumar, Subodh
    TETRAHEDRON LETTERS, 2007, 48 (17) : 3083 - 3087
  • [7] Ratiometric Fluorescent/Colorimetric Cyanide-Selective Sensor Based on Excited-State Intramolecular Charge Transfer-Excited-State Intramolecular Proton Transfer Switching
    Lin, Wei-Chi
    Fang, Sin-Kai
    Hu, Jiun-Wei
    Tsai, Hsing-Yang
    Chen, Kew-Yu
    ANALYTICAL CHEMISTRY, 2014, 86 (10) : 4648 - 4652
  • [8] A colorimetric and ratiometric fluorescent turn-on fluoride chemodosimeter and application in live cell imaging: high selectivity via specific Si-O cleavage in semi aqueous media and prompt recovery of ESIPT along with the X-ray structures
    Goswami, Shyamaprosad
    Das, Avijit Kumar
    Manna, Abhishek
    Maity, Anup Kumar
    Fun, Hoong-Kun
    Quah, Ching Kheng
    Saha, Partha
    TETRAHEDRON LETTERS, 2014, 55 (16) : 2633 - 2638
  • [9] Highly Selective "Turn-On" Fluorescent and Colorimetric Sensing of Fluoride Ion Using 2-(2-Hydroxyphenyl)-2,3-dihydroquinolin-1H)-one based on Excited-State Proton Transfer
    Kanagaraj, Kuppusamy
    Pitchumani, Kasi
    CHEMISTRY-AN ASIAN JOURNAL, 2014, 9 (01) : 146 - 152
1