Synthesis, studies and growth mechanism of ferromagnetic NiFe2O4 nanosheet

被引：79

作者：

Sivakumar, P. ^{[1
]}

Ramesh, R. ^{[2
]}

Ramanand, A. ^{[3
]}

Ponnusamy, S. ^{[2
]}

Muthamizhchelvan, C. ^{[2
]}

机构：

[1] TS Srinivasan Ctr Polytech Coll & Adv Training CP, Dept Basic Engn, Madras 600095, Tamil Nadu, India

[2] SRM Univ, Dept Phys, Ctr Mat Sci & Nano Devices, Kancheepuram 603203, Tamil Nadu, India

[3] Loyola Coll, Dept Phys, Madras 600034, Tamil Nadu, India

来源：

APPLIED SURFACE SCIENCE | 2012年 / 258卷 / 17期

关键词：

NiFe2O4; Nanostructure; Polymer; Chemical synthesis; VSM; MAGNETIC-PROPERTIES; MFE2O4; M; NICKEL; NI; NANOPARTICLES; DELIVERY; POLYMER; CARRIER; TEMPERATURE; CHEMISTRY;

D O I：

10.1016/j.apsusc.2012.03.099

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel ferrite (NiFe2O4) nanoparticles were prepared by a simple and cost-effective method using nickel nitrate, ferric nitrate, ethylene glycol and citric acid via polyvinylpyrrolidone (PVP) assisted sol-gel auto-combustion method. The structure, composition, morphology and magnetic properties of the gel precursor were characterised XRD confirmed the formation of single phase NiFe2O4 with space group Fd3 m and inverse spinel structure and the crystallite size was found to be 29 nm. The FT-IR showed absorption bands, which were assigned to the vibration of tetrahedral and octahedral complexes. The thermal decomposition of the gel precursors was investigated by TGA. HR-SEM and TEM images showed sheet-like nanostructure. The magnetic properties of these nanosheets were studied for the enlightening ferromagnetic behaviour at room temperature. The magnetic saturation (M-s = 41.70 emu g(-1)), remanent magnetisation (M-r = 7.57 emu g(-1)) and coercive force (H-c = 162.47 Oe), were determined. (C) 2012 Elsevier B. V. All rights reserved.

引用

页码：6648 / 6652

页数：5

共 42 条

[1] Thermal degradation and stability of poly(4-vinylpyridine) homopolymer and copolymers of 4-vinylpyridine with methyl acrylate
Azhari, SJ
Diab, MA
[J]. POLYMER DEGRADATION AND STABILITY, 1998, 60 (2-3) : 253 - 256
[2] A facile thermolysis route to monodisperse ferrite nanocrystals
Bao, Ningzhong
Shen, Liming
Wang, Yuhsiang
Padhan, Prahallad
Gupta, Arunava
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (41) : 12374 - +
[3] Preparation and characterization of YADH-bound magnetic nanoparticles
Chen, DH
Liao, MH
[J]. JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2002, 16 (5-6) : 283 - 291
[4] Size-controlled synthesis and magnetic properties of NiFe2O4 hollow nanospheres via a gel-assistant hydrothermal route
Chen, Lingyun
Dai, Hong
Shen, Yongming
Bai, Junfeng
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 491 (1-2) : L33 - L38
[5] Preparation of SrAl2O4:Eu2+, Dy3+ fibers by electrospinning combined with sol-gel process
Cheng, Yongliang
Zhao, Yu
Zhang, Yanfei
Cao, Xueqiang
[J]. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2010, 344 (02) : 321 - 326
[6] Higher-order organization by mesoscale self-assembly and transformation of hybrid nanostructures
Cölfen, H
Mann, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (21) : 2350 - 2365
[7] Mesocrystals:: Inorganic superstructures made by highly parallel crystallization and controlled alignment
Cölfen, H
Antonietti, M
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (35) : 5576 - 5591
[8] Self-propagating high-temperature synthesis of ferrites MFe2O4 (M = Mg, Ba, Co, Ni, Cu, Zn);: reactions in an external magnetic field
Cross, WB
Affleck, L
Kuznetsov, MV
Parkin, IP
Pankhurst, QA
[J]. JOURNAL OF MATERIALS CHEMISTRY, 1999, 9 (10) : 2545 - 2552
[9] Cullity B. D., ELEMENTS XRAY DIFFRA
[10] Dorman J.L., 1992, MAGNETIC PROPERTIES

← 1 2 3 4 5 →