Correlation between hardness and elastic moduli of the ultraincompressible transition metal diborides RuB2, OsB2, and ReB2

被引:194
作者
Chung, Hsiu-Ying [1 ]
Weinberger, Michelle B. [2 ,3 ]
Yang, Jenn-Ming [1 ]
Tolbert, Sarah H. [2 ,3 ]
Kaner, Richard B. [1 ,2 ,3 ]
机构
[1] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
[2] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
[3] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA
基金
美国国家科学基金会;
关键词
D O I
10.1063/1.2946665
中图分类号
O59 [应用物理学];
学科分类号
摘要
The ultraincompressible transition metal diborides RuB2, OsB2, and ReB2 were synthesized by arc melting the elemental metals and boron under an argon atmosphere at ambient pressure. The hardness and Young's modulus were measured using nanoindentation with a Berkovich diamond indenter. The bulk modulus and shear modulus were derived based on an isotropic model and then plotted as a function of hardness. A strong correlation is observed between the hardness and shear modulus for these transition metal diborides. (c) 2008 American Institute of Physics.
引用
收藏
页数:3
相关论文
共 24 条
[1]  
ALEKSANDROV IV, 1987, ZH EKSP TEOR FIZ, V66, P384
[2]  
Brazhkin VV, 2002, PHILOS MAG A, V82, P231, DOI 10.1080/0141861011006774-3
[3]   Structural and electronic properties of OsB2:: A hard metallic material [J].
Chen, Z. Y. ;
Xiang, H. J. ;
Yang, Jinlong ;
Hou, J. G. ;
Zhu, Qingshi .
PHYSICAL REVIEW B, 2006, 74 (01)
[4]   OsB2 and RuB2, ultra-incompressible, hard materials:: First-principles electronic structure calculations [J].
Chiodo, S. ;
Gotsis, H. J. ;
Russo, N. ;
Sicilia, E. .
CHEMICAL PHYSICS LETTERS, 2006, 425 (4-6) :311-314
[5]   Anisotropic mechanical properties of ultra-incompressible, hard osmium diboride [J].
Chung, Hsiu-Ying ;
Yang, J-M. ;
Tolbert, S. H. ;
Kaner, R. B. .
JOURNAL OF MATERIALS RESEARCH, 2008, 23 (06) :1797-1801
[6]   Synthesis of ultra-incompressible superhard rhenium diboride at ambient pressure [J].
Chung, Hsiu-Ying ;
Weinberger, Michelle B. ;
Levine, Jonathan B. ;
Kavner, Abby ;
Yang, Jenn-Ming ;
Tolbert, Sarah H. ;
Kaner, Richard B. .
SCIENCE, 2007, 316 (5823) :436-439
[7]   Osmium diboride, an ultra-incompressible, hard material [J].
Cumberland, RW ;
Weinberger, MB ;
Gilman, JJ ;
Clark, SM ;
Tolbert, SH ;
Kaner, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (20) :7264-7265
[8]  
Frantsevich I.N., 1982, Handbook on elastic constants and moduli of elasticity for metals and nonmetals
[9]   First-principles study of low compressibility osmium borides [J].
Gou, Huiyang ;
Hou, Li ;
Zhang, Jingwu ;
Li, Hui ;
Sun, Guifang ;
Gao, Faming .
APPLIED PHYSICS LETTERS, 2006, 88 (22)
[10]   Synthesis and design of superhard materials [J].
Haines, J ;
Léger, JM ;
Bocquillon, G .
ANNUAL REVIEW OF MATERIALS RESEARCH, 2001, 31 :1-23