Hydrogen bonds dependent assembly of two novel 1D complexes constructed by bis(4-pyridinecarboxamide)alkanes-N,N′-dioxide

被引：6

作者：

Cao, Wei ^{[1
]}

Sun, Hao-Ling ^{[1
]}

Li, Zongsheng ^{[2
]}

机构：

[1] Beijing Normal Univ, Dept Chem, Beijing 100875, Peoples R China

[2] Capital Univ Econ & Business, Coll Safety & Enviroment Engn, Beijing 100070, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2012年 / 19卷

基金：

中国国家自然科学基金;

关键词：

Bis(4-pyridinecarboxamide)alkanes-N; N; '-dioxide; Hydrogen bond; Crystal structure; Thermal stability; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MOLECULAR RODS; 3D; ARCHITECTURES; NETWORKS;

D O I：

10.1016/j.inoche.2012.01.020

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel complexes of CoL1(SCN)(2)(H2O)(2)center dot 4H(2)O (1) and COL2(SCN)(2)(H2O)(2)center dot 2H(2)O (2) (L-1 = bis(4-pyridinecarboxamide)-1,2-ethane-N,N'-dioxide and L-2 = bis(4-pyridinecarboxamide-1,6-hexane)-N,N'-dioxide) constructed by pre-designed ligands of bis(4-pyridinecarboxamide)alkanes-N,N'-dioxide have been synthesized and structurally characterized. Both compounds contain similar 1D chains bridged by the ligands. However, the chains in 1 and 2 are connected by different interchain hydrogen bonds to form different 2D layers, which depend on the flexibility and length of the ligands. Furthermore, the thermal stability of 1 and 2 were studied by using thermogravimetric analysis and temperature dependent powder X-ray diffraction method. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：19 / 22

页数：4

共 40 条

[1] Crystal structure and characterization of organic-inorganic hybridized molecules with molecular zipper structures and two-dimensional grid networks [J].

Ang, SG ;

Sun, BW .

CRYSTAL GROWTH & DESIGN, 2005, 5 (01) :383-386

[2]

[Anonymous], 1996, COMPREHENSIVE SUPRAM

[3]

[Anonymous], NATO SCI SERIES C

[4] Inorganic-organic interpenetrating frameworks:: 4,4′-bipyridine N,N′-dioxide as a bridging hydrogen-bond acceptor [J].

Blake, AJ ;

Brett, MT ;

Champness, NR ;

Khlobystov, AN ;

Long, DL ;

Wilson, C ;

Schröder, M .

CHEMICAL COMMUNICATIONS, 2001, (21) :2258-2259

[5] Tetrahydropoxen:: 2,2′-(1,2-ethanediylbis(iminomethylene))bis(pyridine N-oxide) and its complexes.: X-ray structure of [Cu(H4-poxen)H2O](ClO4)•H2O and [Co(poxen)H2O](ClO4)2 [J].

Boca, R ;

Nemecková, M ;

Vrbová, M ;

Baran, P ;

Svoboda, I ;

Fuess, H .

POLYHEDRON, 2000, 19 (07) :835-839

[6] A rational route to SCM materials based on a 1-D cobalt selenocyanato coordination polymer [J].

Boeckmann, Jan ;

Naether, Christian .

CHEMICAL COMMUNICATIONS, 2011, 47 (25) :7104-7106

[7] In Situ Generated Hydrated Diorganotin Cations as Synthons for Hydrogen-Bonded and Coordination-Driven 1D-, 2D-, and 3D-Assemblies [J].

Chandrasekhar, Vadapalli ;

Singh, Puja .

CRYSTAL GROWTH & DESIGN, 2010, 10 (07) :3077-3093

[8] ONE-DIMENSIONAL COORDINATION POLYMERS - APPLICATIONS TO MATERIAL SCIENCE [J].

CHEN, CT ;

SUSLICK, KS .

COORDINATION CHEMISTRY REVIEWS, 1993, 128 (1-2) :293-322

[9] Supramolecular chemistry at the single-molecule level [J].

Eckel, R ;

Ros, R ;

Decker, B ;

Mattay, J ;

Anselmetti, D .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (03) :484-488

[10] Crystal engineering of NLO materials based on metal-organic coordination networks [J].

Evans, OR ;

Lin, WB .

ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522

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