Study and modeling of heat transfer during the solidification of semi-crystalline polymers

被引:85
|
作者
Le Goff, R
Poutot, G
Delaunay, D
Fulchiron, R
Koscher, E
机构
[1] Univ Nantes, Ecole Polytech, Lab Thermocinet, CNRS,UMR 6607, F-44306 Nantes, France
[2] Univ Lyon 1, CNRS, IMP, UMR 5627,Lab Mat Polymeres & Biomat, F-69622 Villeurbanne, France
关键词
semi-crystalline polymers; crystallization; thermal contact resistance;
D O I
10.1016/j.ijheatmasstransfer.2005.06.015
中图分类号
O414.1 [热力学];
学科分类号
摘要
Semi-crystalline polymers are materials whose behavior during their cooling is difficult to model because of the strong coupling between the crystallization, heat transfer, pressure and shear. Thanks to two original apparatus we study solidification of such a polymer without shear. Firstly the comparison between experimental results and a numerical model will permit to validate crystallization kinetic for cooling rate reachable by DSC, The second experiment makes it possible to analyze solidification for high cooling rate, corresponding to some manufacturing processes. It appears that crystallization has an influence on the thermal contact resistance. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5417 / 5430
页数:14
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