Nanoparticulate TiO2(B): An Anode for Lithium-Ion Batteries

被引：381

作者：

Ren, Yu ^{[1
]}

Liu, Zheng ^{[1
]}

Pourpoint, Frederique ^{[2
]}

Armstrong, A. Robert ^{[1
]}

Grey, Clare P. ^{[2
]}

Bruce, Peter G. ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Cambridge, Dept Chem, Cambridge CB2 1TN, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

anodes; lithium-ion batteries; nanoparticles; titanium dioxide; volumetric capacity; ANATASE-TYPE TIO2; PARTICLE-SIZE; RUTILE TIO2; ROOM-TEMPERATURE; RATE PERFORMANCE; STORAGE; INSERTION; ELECTRODE; CAPABILITY; NANOTUBES;

D O I：

10.1002/anie.201108300

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Small but powerful: TiO 2(B) with the smallest particle size yet reported (2.5 × 4.3-nm) has been synthesized (see TEM image). Its volumetric capacity to store lithium, and hence charge, as an anode in a lithium-ion battery is greater than that of any other titanate at high rates (>1000-mA g -1). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：2164 / 2167

页数：4

共 46 条

[1] Nanostructured Anode Material for High-Power Battery System in Electric Vehicles [J].

Amine, Khalil ;

Belharouak, Ilias ;

Chen, Zonghai ;

Tran, Taison ;

Yumoto, Hiroyuki ;

Ota, Naoki ;

Myung, Seung-Taek ;

Sun, Yang-Kook .

ADVANCED MATERIALS, 2010, 22 (28) :3052-3057

[2] Demonstrating structural deformation in an inorganic nanotube [J].

Andreev, Yuri G. ;

Bruce, Peter G. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (30) :9931-9934

[3]

[Anonymous], 2010, ANGEW CHEM

[4]

[Anonymous], ANGEW CHEM

[5]

[Anonymous], WORLD ELECT VEHICLE

[6] Lithium Coordination Sites in LixTiO2(B): A Structural and Computational Study [J].

Armstrong, A. Robert ;

Arrouvel, Corinne ;

Gentili, Valentina ;

Parker, Stephen C. ;

Islam, M. Saiful ;

Bruce, Peter G. .

CHEMISTRY OF MATERIALS, 2010, 22 (23) :6426-6432

[7] TiO2-B nanowires [J].

Armstrong, AR ;

Armstrong, G ;

Canales, J ;

Bruce, PG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (17) :2286-2288

[8] TiO2(B) nanotubes as negative electrodes for rechargeable lithium batteries [J].

Armstrong, G ;

Armstrong, AR ;

Canales, J ;

Bruce, PG .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (03) :A139-A143

[9] Nanotubes with the TiO2-B structure [J].

Armstrong, G ;

Armstrong, AR ;

Canales, J ;

Bruce, PG .

CHEMICAL COMMUNICATIONS, 2005, (19) :2454-2456

[10] Impact of nanosizing on lithiated rutile TiO2 [J].

Borghols, Wouter J. H. ;

Wagemaker, Marnix ;

Lafont, Ugo ;

Kelder, Erik M. ;

Mulder, Fokko M. .

CHEMISTRY OF MATERIALS, 2008, 20 (09) :2949-2955

← 1 2 3 4 5 →