N,N-Dibromosulfonamides: Versatile Reagents in Organic Synthesis

被引：1
作者：
Hu, Yu-Long [1 ]
Zhou, Ling [1 ]
Chen, Jie [1 ]
机构：
[1] Northwest Univ, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710127, Peoples R China
来源：
CURRENT ORGANIC CHEMISTRY | 2016年 / 20卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Amine; bromination; bromoamine; N; N-dibromosulfonamides; electrophile; oxidation; synthesis; N-HALOSULFONAMIDE; STEREOSELECTIVE-SYNTHESIS; AROMATIC-COMPOUNDS; FACILE GENERATION; ADDITION-REACTION; FREE PROTOCOL; EFFICIENT; BROMINATION; OLEFINS; MILD;
D O I：
10.2174/1385272820666160427122520
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
N,N-Dibromosulfonamides are unique reagents in organic synthesis and have been employed in several areas of application. They have demonstrated high reactivity in bromination reactions, vicinal bromoamine synthesis, in the construction of C-N bonds, and several other transformations. This review describes the scope and application of the N,N-dibromosulfonamides as bromine sources, as amine sources, as sources of both amine and bromine, as oxidation reagents, or as catalysts.
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页码：2083 / 2098
页数：16
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