Accelerated Heck reaction using ortho-palladated complex in a nonaqueous ionic liquid with controlled microwave heating

被引：28

作者：

Hajipour, Abdol R. ^{[1
,2
]}

Rafiee, Fatemeh ^{[1
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran

[2] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2011年 / 25卷 / 07期

关键词：

ortho-palladate; homoveratrylamine; catalyst; Heck reaction; ionic liquid; PALLADIUM-CATALYZED VINYLATION; CORRESPONDING CARBONYL-COMPOUNDS; EFFICIENT CATALYST; ARYL HALIDES; IN-SITU; TETRAALKYLAMMONIUM SALTS; COUPLING REACTIONS; BENZYLIC ALCOHOLS; REACTION MEDIA; BOND FORMATION;

D O I：

10.1002/aoc.1800

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The activity of {Pd[C6H2(CH2CH2NH2)-(OMe)(2),3,4] (mu-Br)}(2) complex was investigated in the Heck-Mizoroki C-C cross-coupling reaction under conventional heating and microwave irradiation conditions in molten salt tetrabutylammonium bromide as the solvent and promoter at 130 degrees C. This complex in these conditions is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even chlorides, and also arenesulfonyl chlorides. Copyright (C) 2011 John Wiley & Sons, Ltd.

引用

页码：542 / 551

页数：10

共 30 条

[1] Accelerated Heck reaction using ortho-palladated complex with controlled microwave heating
Hajipour, Abdol R.
Karami, Kazem
Pirisedigh, Azadeh
APPLIED ORGANOMETALLIC CHEMISTRY, 2009, 23 (12) : 504 - 511
[2] Heck coupling reaction using monomeric ortho-palladated complex of 4-methoxybenzoylmethylenetriphenylphosphorane under microwave irradiation
Hajipour, Abdol R.
Karami, Kazem
Tavakoli, Ghazal
APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (11) : 798 - 804
[3] Application of dimeric ortho-palladated complex of 2-methoxyphenethylamine in the Heck coupling reaction
Hajipour, Abdol R.
Abrishami, Fatemeh
IRANIAN JOURNAL OF CATALYSIS, 2012, 2 (03): : 95 - 100
[4] An efficient Stille cross-coupling reaction catalyzed by ortho-palladated complex of tribenzylamine under microwave irradiation
Hajipour, Abdol R.
Karami, Kazem
Rafiee, Fatemeh
APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (01) : 27 - 31
[5] Application of ortho-palladated homoveratrylamine complex containing mixed phosphorus-nitrogen donors in the Suzuki reaction
Hajipour, Abdol R.
Rahimi, Hannaneh
Rafiee, Fatemeh
APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (09) : 467 - 470
[6] Microwave-assisted Suzuki Cross-Coupling Reactions using Dimeric ortho-palladated Complex of Tribenzylamine
Hajipour, Abdol Reza
Rafiee, Fatemeh
ORGANIC PREPARATIONS AND PROCEDURES INTERNATIONAL, 2013, 45 (06) : 465 - 472
[7] Application of a dimeric ortho-palladated complex of tribenzylamine as an efficient catalyst in microwave-assisted Hiyama coupling reactions
Hajipour, Abdol R.
Rafiee, Fatemeh
APPLIED ORGANOMETALLIC CHEMISTRY, 2012, 26 (02) : 51 - 55
[8] Microwave-enhanced cyanation of aryl halides with a dimeric ortho-palladated complex catalyst
Abdol-Reza Hajipour
Fatemeh Abrisham
Ghazal Tavakoli
Transition Metal Chemistry, 2011, 36 : 725 - 730
[9] Application of dimeric and monomeric ortho-palladated complexes as an efficient catalysts for Heck cross-coupling reaction
Naghipour, Ali
Sayadi, Mohsen
Hashemi, Mojdeh
Kazemi, Mosstafa
IRANIAN CHEMICAL COMMUNICATION, 2013, 1 (01) : 69 - 82
[10] CN-Dimeric ortho-palladated complex catalyzed cyanation of aryl halides under microwave irradiation
Hajipour, Abdol Reza
Rafiee, Fatemeh
JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2014, 11 (05) : 1391 - 1395

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