Thermodynamics of oxygenate fuel additives as a function of temperature

被引：32

作者：

Gonzalez-Olmos, R. ^{[1
]}

Iglesias, M. ^{[1
]}

Santos, B. M. R. P. ^{[2
]}

Mattedi, S. ^{[2
]}

机构：

[1] Univ Rovira & Virgili, Escola Tecn Super Engn Quim, Dept Engn Quim, Tarragona 43007, Spain

[2] Univ Fed Bahia, Escola Politecn, Dept Engn Quim, BR-40210 Salvador, BA, Brazil

来源：

PHYSICS AND CHEMISTRY OF LIQUIDS | 2008年 / 46卷 / 03期

关键词：

ether; theoretical model; density; ultrasonic velocity; prediction; temperature;

D O I：

10.1080/00319100701660411

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This article reports experimental data of density and ultrasonic velocity at the range from 278.15 to 323.15 K and atmospheric pressure of ethers used as additives in fuels (methyl tert-butyl ether ethyl tert-butyl ether, tert-amyl ether and diisopropyl ether). From the experimental data, temperature dependent polynomials were fitted and theoretical models were used to correlate these properties. The MTC Lattice Gas EOS is used to correlate simultaneously vapour pressures and volumetric properties. Free Length Theory is applied to estimate the ultrasonic velocity of the chemicals as a function of temperature, satisfactory predictions were obtained. The dependence of temperature showed by these magnitudes reveals a strong interaction at low values.

引用

页码：223 / 237

页数：15

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