Plasticization lags behind water migration in nylon-6: An NMR imaging and relaxation study

被引：20

作者：

Reuvers, N. J. W. ^{[2
]}

Huinink, H. P. ^{[2
]}

Adan, O. C. G. ^{[1
,2
]}

机构：

[1] TNO, NL-5600 HE Eindhoven, Netherlands

[2] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands

来源：

POLYMER | 2015年 / 63卷

关键词：

Nylon; NMR; Relaxation; GLASS-TRANSITION TEMPERATURE; FILMS; PART; DESORPTION; ABSORPTION; DIFFUSION; MOBILITY; SORPTION; FIBERS; PHASE;

D O I：

10.1016/j.polymer.2015.03.005

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The water sorption mechanism in thin nylon 6 films is studied by H-1 NMR imaging and relaxometry. Experiments using D2O and H2O enable identification of polymer and water signal components during the uptake process. Tracking the mobility and size of polymer and water components gives new insights into the water sorption mechanism of nylon 6. H-1 NMR imaging and relaxometry it is shown that water uptake is faster than plasticization. Water arrives first in the polymer matrix. After a while plasticization starts. Plasticization continues even when the nylon matrix is fully saturated. Further it is observed that the water mobility is still increasing, when the matrix is both saturated by water and plasticized. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：127 / 133

页数：7

共 35 条

[31] Quantitative Water Uptake Study in Thin Nylon-6 Films with NMR Imaging [J].

Reuvers, N. J. W. ;

Huinink, H. P. ;

Fischer, H. R. ;

Adan, O. C. G. .

MACROMOLECULES, 2012, 45 (04) :1937-1945

[32] Water Plasticizes Only a Small Part of the Amorphous Phase in Nylon-6 [J].

Reuvers, Nicolaas ;

Huinink, Hendrik ;

Adan, Olaf .

MACROMOLECULAR RAPID COMMUNICATIONS, 2013, 34 (11) :949-953

[33] PULSED NMR-STUDIES OF MOLECULAR-MOTION IN WET NYLON-6,6 FIBERS [J].

SMITH, EG .

POLYMER, 1976, 17 (09) :761-767

[34] DIELECTRIC-PROPERTIES OF POLYAMIDE-4,6 [J].

STEEMAN, PAM ;

MAURER, FHJ .

POLYMER, 1992, 33 (20) :4236-4241

[35] High spatial resolution NMR imaging of polymer layers on metallic substrates [J].

Zhu, Haijin ;

Huinink, Hendrik P. ;

Erich, Sebastiaan J. F. ;

Baukh, Viktor ;

Adan, Olaf C. G. ;

Kopinga, Klaas .

JOURNAL OF MAGNETIC RESONANCE, 2012, 214 :227-236

← 1 2 3 4 →