Aerobic, Cu-catalyzed desulfitative C-C bond-forming reaction of ketene dithioacetals/vinylogous thioesters and arylboronic acids

被引：44

作者：

Dong, Ying ^{[1
]}

Wang, Mang ^{[1
,2
]}

Liu, Jun ^{[1
]}

Ma, Wei ^{[1
]}

Liu, Qun ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

[2] Nankai Univ, State Key Lab Elemento Organ Chem, Tianjin 300071, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 26期

关键词：

BORONIC ACIDS; TETRASUBSTITUTED OLEFINS; ORGANOBORON COMPOUNDS; COPPER; ESTERS; BENZOFURANS; TRI;

D O I：

10.1039/c1cc11382h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new Cu-catalyzed thioorganic-boronic acid desulfitative C-C bond-forming reaction involving ketene dithioacetals/ vinylogous thioesters is reported to proceed without the assistance of ligating S-pendant. Vinylogous thiolesters and tetrasubstituted olefins were prepared by this reaction in which Cu catalyst plays a dual role under aerobic conditions.

引用

页码：7380 / 7382

页数：3

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