Nickel-Catalyzed Phosphorylation of Tosylates

被引：14
作者：
Li, Chun-jing [1 ]
机构：
[1] Hebei Chem & Pharmaceut Coll, Dept Chem & Environm Engn, Shijiazhuang 050026, Hebei, Peoples R China
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 04期
关键词：
aryl tosylates; C-P coupling; nickel-catalyzed; CROSS-COUPLING REACTIONS; ARYL MESYLATES;
D O I：
10.1134/S1070363220040258
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four new bidentate phosphine ligands have been synthesized, characterized and evaluated in Ni-catalyzed C-P coupling reaction. The readily available and inexpensive highly active sulfonate Ni(cod)(2)-L8catalyzes the reaction leading to the desired aryl phosphonates accumulated with moderate to excellent yields. This method is characterized by good functional groups tolerance, wide substrate scope, and easy scaling up.
引用
收藏
页码：725 / 730
页数：6
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