Nickel-Catalyzed Phosphorylation of Tosylates

被引：14
作者：
Li, Chun-jing [1 ]
机构：
[1] Hebei Chem & Pharmaceut Coll, Dept Chem & Environm Engn, Shijiazhuang 050026, Hebei, Peoples R China
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2020年 / 90卷 / 04期
关键词：
aryl tosylates; C-P coupling; nickel-catalyzed; CROSS-COUPLING REACTIONS; ARYL MESYLATES;
D O I：
10.1134/S1070363220040258
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Four new bidentate phosphine ligands have been synthesized, characterized and evaluated in Ni-catalyzed C-P coupling reaction. The readily available and inexpensive highly active sulfonate Ni(cod)(2)-L8catalyzes the reaction leading to the desired aryl phosphonates accumulated with moderate to excellent yields. This method is characterized by good functional groups tolerance, wide substrate scope, and easy scaling up.
引用
收藏
页码：725 / 730
页数：6
相关论文
共 50 条
  • [31] Nickel-Catalyzed Synthesis of Silanes from Silyl Ketones
    Srimontree, Watchara
    Lakornwong, Waranya
    Rueping, Magnus
    ORGANIC LETTERS, 2019, 21 (23) : 9330 - 9333
  • [32] Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes
    Derosa, Joseph
    Apolinar, Omar
    Kang, Taeho
    Tran, Van T.
    Engle, Keary M.
    CHEMICAL SCIENCE, 2020, 11 (17) : 4287 - 4296
  • [33] Stereospecific Nickel-Catalyzed Borylation of Secondary Benzyl Pivalates
    Martin-Montero, R.
    Krolikowski, T.
    Zarate, C.
    Manzano, R.
    Martin, R.
    SYNLETT, 2017, 28 (19) : 2604 - 2608
  • [34] Nickel-Catalyzed 1,2-Arylboration of Vinylarenes
    Wang, Wang
    Ding, Chao
    Pang, Hailiang
    Yin, Guoyin
    ORGANIC LETTERS, 2019, 21 (11) : 3968 - 3971
  • [35] Nickel-Catalyzed Enantioselective Reductive Aryl Fluoroalkenylation of Alkenes
    Ma, Teng
    Chen, Yate
    Li, Yuxiu
    Ping, Yuanyuan
    Kong, Wangqing
    ACS CATALYSIS, 2019, 9 (10): : 9127 - 9133
  • [36] Nickel-Catalyzed Cyanation of Benzylic and Allylic Pivalate Esters
    Michel, Nicholas W. M.
    Jeanneret, Alexandria D. M.
    Kim, Hyehwang
    Rousseaux, Sophie A. L.
    JOURNAL OF ORGANIC CHEMISTRY, 2018, 83 (19) : 11860 - 11872
  • [37] Nickel-catalyzed decarboxylative cycloaddition of isatoic anhydrides with alkenes
    Sun, Meng
    Ma, Yan-Na
    Li, Ya-Min
    Tian, Qiu-Ping
    Yang, Shang-Dong
    TETRAHEDRON LETTERS, 2013, 54 (37) : 5091 - 5095
  • [38] Nickel-catalyzed intermolecular carboiodination of alkynes with aryl iodides
    Takahashi, Toshifumi
    Kuroda, Daiki
    Kuwano, Toru
    Yoshida, Yuji
    Kurahashi, Takuya
    Matsubara, Seijiro
    CHEMICAL COMMUNICATIONS, 2018, 54 (90) : 12750 - 12753
  • [39] Nickel-Catalyzed Decarboxylative Difluoroalkylation of ,-Unsaturated Carboxylic Acids
    Li, Gang
    Wang, Tao
    Fei, Fan
    Su, Yi-Ming
    Li, Yan
    Lan, Quan
    Wang, Xi-Sheng
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (10) : 3491 - 3495
  • [40] Nickel-Catalyzed Allylic Substitution Reactions: An Evolving Alternative
    Ghorai, Debasish
    Cristofol, Alex
    Kleij, Arjan W.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2022, 2022 (02)
12345