Carbonyl complexes of manganese, rhenium and molybdenum with 2-pyridylimino acid ligands

被引：40

作者：

Alvarez, Celedonio M. ^{[1
]}

Garcia-Rodriguez, Raul ^{[1
]}

Miguel, Daniel ^{[1
]}

机构：

[1] Univ Valladolid, Fac Ciencias, IU CINQUIMA Quim Inorgan, E-47005 Valladolid, Spain

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 26期

关键词：

pyridylimino acid ligands; carbonyl complexes; Schiff bases;

D O I：

10.1016/j.jorganchem.2007.09.025

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

MBr(CO)(3){k(2) (N, O)-pyca}] [M = Mn(1a), Re(1b), pyca = pyridine-2-carboxaldehyde] and [MoCl(eta(3)-C3H4Me-2)(CO)(2){k(2) (N, O)-pyca}] (1c) react with aminoacid beta-alanine to give the corresponding iminopyridine complexes 2a-2c. The same method affords the iminopyridine derivatives from gamma-aminobutyric acid (GABA) (3a-3c) and 3-aminobenzoic acid (4a-4c). For complexes 2a-2c, 3a, 3c and 4a, the solid state structures have been determined by X-ray crystallography, revealing interesting differences in their hydrogenbonding patterns in solid state. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：5717 / 5726

页数：10

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