Characterization of a metastable state of ozone by high-resolution Fourier transform spectrometry

被引：23
作者：
Bouvier, AJ
Bacis, R
Bussery, B
Churassy, S
Inard, D
Nota, M
Brion, J
Malicet, J
Anderson, SM
机构：
[1] FAC SCI REIMS,CHIM PHYS LAB,GMSA,CNRS URAD 1434,F-51062 REIMS,FRANCE
[2] MAX PLANCK INST KERNPHYS,BEREICH ATMOSPHARENPHYS,D-69029 HEIDELBERG,GERMANY
来源：
CHEMICAL PHYSICS LETTERS | 1996年 / 255卷 / 4-6期
关键词：
D O I：
10.1016/0009-2614(96)00370-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report a high-resolution study of the Wulf bands of ozone. A preliminary analysis of the rotational structure in two vibronic bands yields the band origin T-0 = 9555.49 +/- 0.25 cm(-1), the bending frequency omega(2) = 530.9 +/- 0.4 cm(-1) and geometries (R, theta) for the corresponding bound vibrational levels of the upper state, which is most likely to be (3)A(2). Rotational levels extend to at least 1090 cm(-1) above T-0. The radiative lifetime is approximate to 0.1-0.01 s, indicating the state's metastable character.
引用
收藏
页码：263 / 266
页数：4
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