SO3H-functionalized hollow mesoporous carbon sphere prepared by simultaneously achieving sulfonation and hollow structure

被引:15
作者
Chang, Binbin [1 ]
Li, Yanchun [1 ]
Guo, Yanzhen [1 ]
Yin, Hang [1 ]
Zhang, Shouren [1 ]
Yang, Baocheng [1 ]
机构
[1] Huanghe Sci & Technol Coll, Inst Nanostruct Funct Mat, Zhengzhou 450006, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon materials; Mesoporous; Hollow sphere; Sulfonation; SOLID ACID CATALYST; EFFICIENT;
D O I
10.1007/s10934-015-9935-7
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
SO3H-functionalized hollow mesoporous carbon sphere (HMCS-SO3H) was successfully synthesized via a facile strategy using inexpensive resins as precursor in combination with metal oxide template. By the one-step thermal treatment with sulfuric acid, it simultaneously achieved the formation of hollow spherical structure and sulfonation functionalization. HMCS-SO3H catalyst possessed superior mesoporosity, uniform sphere morphology and high acidity, which endowed it excellently catalytic property for esterification of oleic acid. In addition, HMCS-SO3H exhibited prominent stability and reusability.
引用
收藏
页码:629 / 634
页数:6
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