SO3H-functionalized hollow mesoporous carbon sphere prepared by simultaneously achieving sulfonation and hollow structure

被引：16

作者：

Chang, Binbin ^{[1
]}

Li, Yanchun ^{[1
]}

Guo, Yanzhen ^{[1
]}

Yin, Hang ^{[1
]}

Zhang, Shouren ^{[1
]}

Yang, Baocheng ^{[1
]}

机构：

[1] Huanghe Sci & Technol Coll, Inst Nanostruct Funct Mat, Zhengzhou 450006, Henan, Peoples R China

来源：

JOURNAL OF POROUS MATERIALS | 2015年 / 22卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Carbon materials; Mesoporous; Hollow sphere; Sulfonation; SOLID ACID CATALYST; EFFICIENT;

D O I：

10.1007/s10934-015-9935-7

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

SO3H-functionalized hollow mesoporous carbon sphere (HMCS-SO3H) was successfully synthesized via a facile strategy using inexpensive resins as precursor in combination with metal oxide template. By the one-step thermal treatment with sulfuric acid, it simultaneously achieved the formation of hollow spherical structure and sulfonation functionalization. HMCS-SO3H catalyst possessed superior mesoporosity, uniform sphere morphology and high acidity, which endowed it excellently catalytic property for esterification of oleic acid. In addition, HMCS-SO3H exhibited prominent stability and reusability.

引用

页码：629 / 634

页数：6

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