Polymerization of an azastyrene derivative .1. 1,6-addition polymerization of 2,6-diisopropyl-N-methyleneaniline

被引：6

作者：

Hashidzume, A ^{[1
]}

Kajiwara, A ^{[1
]}

Harada, A ^{[1
]}

Kamachi, M ^{[1
]}

机构：

[1] OSAKA UNIV,FAC SCI,DEPT MACROMOL SCI,TOYONAKA,OSAKA 560,JAPAN

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1996年 / 17卷 / 08期

关键词：

D O I：

10.1002/marc.1996.030170805

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The polymerizability of an azastyrene derivative, 2,6-diisopropyl-N-methyleneaniline (DiPMAn), was studied. Although DiPMAn could not be polymerized by radical and anionic initiators, it was polymerized with cationic initiators, such as trifluoroacetic acid (TFA), TiCl4-TFA, and SnCl4-TFA. The polymer is formed by 1,6-addition with electrophilic substitution of an activated monomer in para-position of the aromatic ring.

引用

页码：529 / 537

页数：9

共 26 条

[1] BAILEY WJ, 1968, POLYM PREPR, V9, P404
[2] REINVESTIGATION OF THE FORMALDEHYDE ANILINE CONDENSATION .4. ULTRAVIOLET PHOTOELECTRON AND ELECTRON TRANSMISSION SPECTRA OF N-METHYLENEANILINE AND ITS SYMMETRIC DIMETHYL RING-SUBSTITUTED HOMOLOGS AND SEMIEMPIRICAL THEORETICAL EVALUATIONS
DISTEFANO, G
GIUMANINI, AG
MODELLI, A
POGGI, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1985, (10): : 1623 - 1627
[3] Emsley J. W., 1966, HIGH RESOLUTION NUCL, V2
[4] REVISITATION OF FORMALDEHYDE ANILINE CONDENSATION .8. MONOMERIC N-METHYLENE ANILINES
GIUMANINI, AG
VERARDO, G
POIANA, M
[J]. JOURNAL FUR PRAKTISCHE CHEMIE, 1988, 330 (02): : 161 - 324
[5] SYNTHESIS OF NEW RIGID-ROD HELICAL POLYMERS THROUGH THE LIVING POLYMERIZATION OF CARBODIIMIDES USING TITANIUM(IV) COMPLEXES
GOODWIN, A
NOVAK, BM
[J]. MACROMOLECULES, 1994, 27 (19) : 5520 - 5522
[6] GULMAN H, 1944, J AM CHEM SOC, V66, P1515
[7] SYNTHESIS AND POLYMERIZATION OF IMINES AND AZADIENES - NEW POLYMERIZABLE MONOMERS
HALL, HK
[J]. MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 54-5 : 73 - 81
[8] POLYMERIZATION OF AZABUTADIENE (AZINE) DERIVATIVES - PREPARATION OF A STEREOREGULAR POLYMER FROM PROPIONALDEHYDE AZINE
HARADA, A
FUJII, H
KAMACHI, M
[J]. MACROMOLECULES, 1991, 24 (20) : 5504 - 5507
[9] ANIONIC-POLYMERIZATION OF NORMAL-BUTYRALDEHYDE AZINE TO CRYSTALLINE TRANS-1,4-POLY(NORMAL-BUTYRALDEHYDE AZINE)
HARADA, A
KAJIWARA, A
FUJII, H
KAMACHI, M
[J]. POLYMER JOURNAL, 1992, 24 (09) : 931 - 938
[10] POLYMERIZATION OF TRIFLUOROACETALDEHYDE AZINE (1,1,1,6,6,6-HEXAFLUORO-3,4-DIAZA-2,4-HEXADIENE)
HASHIDZUME, A
KAJIWARA, A
HARADA, A
KAMACHI, M
[J]. MACROMOLECULES, 1995, 28 (02) : 417 - 420

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