Reduction of CO2 into Methylene Coupled with the Formation of C-S Bonds under NaBH4/I2 System

被引：33

作者：

Guo, Zhigiang ^{[1
,2
]}

Zhang, Bo ^{[2
]}

Wei, Xuehong ^{[1
]}

Xi, Chanjuan ^{[2
]}

机构：

[1] Shanxi Univ, Sci Instrument Ctr, Taiyuan 030006, Peoples R China

[2] Tsinghua Univ, Dept Chem, MOE Key Lab Bioorgan Phosphorus Chem & Chem Biol, Beijing 100084, Peoples R China

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 21期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; ORGANIC DISULFIDES; TRANSFORMATION; DITHIOACETALS; LUMINESCENCE; SUBSTANCES; CATALYSIS; POLYMERS; HYDROGEN; AMINALS;

D O I：

10.1021/acs.orglett.8b02730

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A selective four-electron reduction of CO2 with thiophenol using NaBH4 as a reductant is described to access dithioacetals. This reaction provides a novel synthetic method for the highly selective conversion of CO2 into methylene, and a new access to molecular structures via formation of C-S bonds using CO2 as the Cl source.

引用

页码：6678 / 6681

页数：4

共 41 条

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