Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides

被引：10

作者：

Bukovec, Christian ^{[1
]}

Kazmaier, Uli ^{[1
]}

机构：

[1] Univ Saarland, Inst Organ Chem, D-66123 Saarbrucken, Germany

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2011年 / 9卷 / 08期

关键词：

MOLYBDENUM-CATALYZED HYDROSTANNATION; REGIOSELECTIVE HYDROSTANNATIONS; IMPROVED PROTOCOLS; NATURAL-PRODUCTS; CHEMICAL SPACE; KEY STEPS; ALKYLATIONS;

D O I：

10.1039/c0ob00945h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized buiding blocks in excellent yields.

引用

页码：2743 / 2750

页数：8

共 9 条

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