Ethylene trimerization with a half-sandwich titanium complex bearing a pendant thienyl group

被引：63

作者：

Huang, JL ^{[1
]}

Wu, TZ ^{[1
]}

Qian, YL ^{[1
]}

机构：

[1] E China Univ Sci & Technol, Organomet Chem Lab, Shanghai 200237, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 22期

关键词：

D O I：

10.1039/b309749h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A half-sandwich titanium complex with a pendant thienyl group, activated by methylalumoxane (MAO), can trimerize ethylene to 1-hexene with considerable activity and high selectivity; the coodination of the sulfur atom to the titanium center is proposed to be responsible for the selective trimerization of ethylene.

引用

页码：2816 / 2817

页数：2

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