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Optical transition properties of Eu3+ in Eu(DBM)3phen mono-dispersed microspheres for microcavity laser application
被引:21
作者:
Huang, Libo
[1
]
Cheng, Lihong
[1
]
Yu, Hongquan
[2
]
Zhou, Le
[2
]
Sun, Jiashi
[1
]
Zhong, Haiyang
[1
]
Li, Xiangping
[1
]
Zhang, Jinsu
[1
]
Tian, Yue
[1
]
Zheng, Yanfeng
[1
]
Yu, Tingting
[1
]
Wang, Juan
[3
]
Chen, Baojiu
[1
]
机构:
[1] Dalian Maritime Univ, Dept Phys, Dalian 116026, Liaoning, Peoples R China
[2] Dalian Jiaotong Univ, Coll Environm & Chem Engn, Dalian 116028, Liaoning, Peoples R China
[3] Tianjin Engn Tech Inst, Dept Informat Engn, Tianjin 300280, Peoples R China
基金:
中国国家自然科学基金;
关键词:
Luminescence;
Judd-Ofelt theory;
Optical intensity parameters;
POLY(METHYL METHACRYLATE);
EU(III) IONS;
EUROPIUM;
LUMINESCENCE;
COMPLEXES;
GLASS;
PARAMETERS;
LIGANDS;
SYSTEMS;
PMMA;
D O I:
10.1016/j.physb.2011.04.019
中图分类号:
O469 [凝聚态物理学];
学科分类号:
070205 ;
摘要:
Mono-dispersed microspheres of ternary complex Eu(DBM)(3)phen (DBM=dibenzoylmethide; phen= 1,10-phenanthroline) were prepared through a facile process. The obtained sample was characterized by means of X-ray powder diffraction (XRD) and scanning electron microscope (SEM). And the luminescence properties of the Eu(DBM)(3)phen were investigated by the fluorescence spectra and the fluorescence decay. According to Judd-Ofelt theory, the optical transition intensity parameters Omega(lambda) (lambda=2, 4 and 6) were obtained to be 20.99 x 10(-2), 0.98 x 10(-20) and 1.79 x 10(-20) cm(2), respectively. The radiative transition properties of D-5(0) level, including transition rates, branch ratios and radiative transition lifetime were calculated. As a potential material for microsphere lasers, the optical gain performance for D-5(0)-> F-7(2) transition was also evaluated. (C) 2011 Elsevier B.V. All rights reserved.
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页码:2745 / 2749
页数:5
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