Structure and magnetic ordering of KxH1-xNi(OH2)4[Ru2(CO3)4]•zH2O

被引：25
作者：
Kennon, Bretni S.
Her, Jae-Hyuk
Stephens, Peter W. [1 ]
Shum, William W.
Miller, Joel S.
机构：
[1] SUNY Stony Brook, Dept Phys & Astron, Stony Brook, NY 11794 USA
[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 22期
关键词：
D O I：
10.1021/ic701318q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
KxH1-xNi(OH2)(4)[Ru-2(CO3)(4)]center dot zH(2)O is a ferrimagnet (T-c = 4.3 K) formed from the reaction of K-3[Ru(II/III)2(CO3)(4)] and Ni-II in water. It possesses a new 3-D network structural motif composed of linked chains and mu(3)-CO3 linkages to both Ru and Ni sites. Each Ni(II) bonds to four oxygens and to two [Ru-2(CO3)(4)](3-) moieties in a cis manner, and four mu(3)-CO3 groups from each [Ru-2(CO3)(4)](3-) have two oxygens bonding to the Ru-2 moiety, forming the typical paddle-wheel core, and trans pairs of the third CO32- oxygen axially bonded to either another Ru-2 or Ni-ll.
引用
收藏
页码：9033 / 9035
页数：3
相关论文
共 50 条
[31]   TERMINAL WATER LIGAND-EXCHANGE AND SUBSTITUTION BY ISONICOTINAMIDE ON THE OXO-CENTERED TRIRUTHENIUM(III) COMPLEX [RU-3(MU(3)-O)(MU-CH3CO2)(6)(OH2)(3)](+) - CRYSTAL-STRUCTURE OF [RU-3(MU(3)-O)(MU-CH3CO2)(6)(OH2)(3)]CLO4.HCLO4.H2O [J].
POWELL, G ;
RICHENS, DT ;
POWELL, AK .
INORGANICA CHIMICA ACTA, 1993, 213 (1-2) :147-155
[32]   CRYSTALLINE STRUCTURE OF (NH4)6ZR2(OH)2(CO3)6.3H2O [J].
GORBUNOVA, YE ;
NOVITSKA.GN ;
KUZNETSO.VG .
ZHURNAL STRUKTURNOI KHIMII, 1970, 11 (03) :560-+
[33]   Dynamics of the frustrated spin in the low dimensional magnet Co3(OH)2(C4O4)2 [J].
Mole, Richard A. ;
Rule, Kirrily C. ;
Yu, Dehong ;
Stride, John A. ;
Nadeem, M. Arif ;
Wood, Paul T. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2016, 28 (12)
[34]   STRUCTURE REFINEMENT OF CO3(OH)2(PO3OH)2 AND CO[PO2(OH)2]2.2H2O [J].
EFFENBERGER, H .
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1992, 48 :2104-2107
[35]   Crystal structure of susannite, Pb4SO4(CO3)2(OH)2:: a trimorph with macphersonite and leadhillite [J].
Steele, IM ;
Pluth, JJ ;
Livingstone, A .
EUROPEAN JOURNAL OF MINERALOGY, 1999, 11 (03) :493-499
[36]   Na3[Ru2(μ-CO3)4] as a Homogeneous Catalyst for Water Oxidation; HCO3- as a Co-Catalyst [J].
Patra, Shanti Gopal ;
Mondal, Totan ;
Sathiyan, Krishnamoorthy ;
Mizrahi, Amir ;
Kornweitz, Haya ;
Meyerstein, Dan .
CATALYSTS, 2021, 11 (02) :1-21
[37]   CRYSTAL-STRUCTURE OF [PB4(OH)4]3(CO3)(CLO4)10.6H2O [J].
HONG, SH ;
OLIN, A .
ACTA CHEMICA SCANDINAVICA, 1973, 27 (07) :2309-2320
[38]   Ru2(DMBA)4(BF4)2 and Ru2(DMBA)4(NO3)2:: the first examples of diruthenium compounds containing BF4- and NO3- as ligands [J].
Xu, GL ;
Jablonski, CG ;
Ren, T .
INORGANICA CHIMICA ACTA, 2003, 343 :387-390
[39]   Pr6O11+Yb2O3对α-Ni0.8Co0.04Al0.16（OH）2.2-2y（CO3）y·zH2O正极材料的改性 [J].
庄玉贵 ;
陈秀宇 ;
林谦 ;
邹文桐 .
南开大学学报(自然科学版), 2012, 45 (04) :13-17
[40]   Hydrogen-bonding interactions in the series of complexes [M(C4O4)(OH2)2(dmf)2] and [M(C4O4)(OH2)4] (M = Mn, Co, Ni, Cu, Zn) [J].
Alleyne, BD ;
Hall, LA ;
Hosein, HA ;
Jaggernauth, H ;
White, AJP ;
Williams, DJ .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (22) :3845-3850
12345