P-ρ-T Data for Carbon Dioxide from (310 to 450) K up to 160 MPa

被引:26
作者
Mantilla, Ivan D. [1 ]
Cristancho, Diego E. [1 ]
Ejaz, Saquib [1 ]
Hall, Kenneth R. [1 ]
Atilhan, Mert [2 ]
Iglesias-Silva, Gustavo A.
机构
[1] Texas A&M Univ, Artie McFerrin Dept Chem Engn, College Stn, TX 77843 USA
[2] Qatar Univ, Dept Chem Engn, Doha, Qatar
关键词
VIRIAL-COEFFICIENTS; TEMPERATURE-RANGE; PRESSURES; DENSITY; METHANE; GAS;
D O I
10.1021/je1001158
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper presents P-rho-T data for pure carbon dioxide measured with a high-pressure single-sinker magnetic suspension densimeter (MSD). The data cover four isotherms (310, 350, 400, 450) K. The MSD technique yields data with less than 0.03 % relative uncertainty over the pressure range of (10 to 200) MPa. A comparison of the experimental data to the equation of state developed by Span and Wagner indicates that the equation and the data are consistent within the low range of pressure. The reference equation has a relative uncertainty of +/- 0.03 % to +/- 0.05 % below 30 MPa. At higher pressures, the density predictions of this model agree with the experimental data with a maximum relative deviation of 0.1 %.
引用
收藏
页码:4611 / 4613
页数:3
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