Derivation of the phase factor and geometrical phase for an N-state degenerate system

被引:7
作者
Baer, M [1 ]
机构
[1] Soreq NRC, Dept Appl Math & Phys, IL-81800 Yavne, Israel
关键词
D O I
10.1063/1.476629
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This work considers the case of degenerate vibronic coupling of N states all at one single;point. For this case we first derived the extended Single-state Born-Oppenheimer equation [M. Baer and R. Englman, Chem. Phys. Lett. 265, 105 (1997)] and then showed that such a system, Like the two-state system, can be described in terms of a single phase factor and is characterized by a well-defined geometrical phase. (C) 1998 American Institute of Physics.
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收藏
页码:891 / 894
页数:4
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