Nonlinear optical properties of the salts of "diffuse" anions

被引：4
|
作者：
Yeates, AT [1 ]
Dudis, DS [1 ]
Wilkes, JS [1 ]
机构：
[1] USAF, Res Lab, Wright Patterson AFB, OH 45433 USA
来源：
LINEAR, NONLINEAR, AND POWER-LIMITING ORGANICS | 2000年 / 4106卷
关键词：
D O I：
10.1117/12.408521
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new class of materials, which demonstrates a potentially high third-order nonlinear optical (NLO) response based on highly polarizable anions, is discussed. Two examples of such ions included in this article are trithiocarbonate (CS32-) and aci-nitro-dithioacetate (NO2CHCS22-). The NLO response of any real materials containing these ions will be highly dependent on the nature of the cation present. It is expected that smaller and more localizing cations will have a smaller NLO response. We have performed ab initio finite-field computations of several anions along with some salts of the aci-nitro-dithioacetate anion to illustrate this effect.
引用
收藏
页码：334 / 337
页数：4
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